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NO. Title Presented at
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Date
Author Project Team / Research Division
Abstract
10986
Poro-mechanical/chemical coupling analysis of borehole instability in heterogeneous shale
3rd Biot Conference on Poromechanics
2005/5/25
Koji Yamamoto, Teruyuki Koyama(Japan Oil, Gas and Metals National Corporation), Younane Abousleiman(The University of Oklahoma)
Petroleum Engineering Research Team
[Abstract] This paper describes a process to tackle with wellbore stability problems occurring in a shale formation of an oil field. In the formation, conventional homogeneous, linear elastic, and isotropic model could not explain the phenomena occurred. Instead, fluid-solid coupling ideas are fully utilized not only to explain the phenomena, but also determine the mud weight window quantitatively. Also, chemical effects of the drilling fluid are considered to reduce the drilling troubles. Phenomenological and numerical models and used techniques are discussed along with the schematic flow of the study.
10981
Hydrogen Production with Steam Reformign of Dimethyl Ether
10th Japan-Korea Symposium on Catalysis
2005/5/12
Kaoru Takeishi(Shizuoka University)
Research Project Team on Emerging Gas Technologies
[Abstract] Steam reforming of methanol and gasoline are actively researched as hydrogen supply methods for fuel cells of vehicles, and so on. However, these materials have problems such as the infrastructure, toxicity, difficulty of reforming, and so forth. Dimethyl ether (DME) is expected as one of clean fuels, and DME is one of substitutes of diesel fuels and LPG. Infrastructures of LPG will be able to use for DME. Therefore, we have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by a sol-gel method produced large quantities of H2 and CO2 with DME steam reforming at 300 ℃. Other metal alumina catalysts prepared by the sol-gel method produced H2 and CO2, but also produced large quantities of CO. Our studies showed that copper is the best metal for the production of H2 while producing less CO. Γ-alumina for DME hydrolysis into methanol, and copper for methanol steam reforming to H2 and CO2 coexist on the surfaces of catalysts prepared by the sol-gel method, and the catalysts produce more H2 from DME than impregnation catalysts, mixed catalysts, and so on. We have developed a great potential for H2 supply from DME.
10973
Scientific Results of the METI 2004 Nankai Trough Gas Hydrate Drilling and Testing Project
AAPG Hedberg Conference
2004/9/13
Yoshihiro Tsuji(Japan Oil, Gas and Metals National Corporation)
Methane Hydrate Research Project Team
[Abstract] The Nankai Trough is a depression between the Philippine Sea Plate to the southeast and the Eurasian Plate to the northwest, extending along central Honshu to Shikoku in the south and to the east of Kyushu. From late 1999 to early 2000, MITI Nankai Trough wells for research on methane hydrate in resource potential evaluation point of view were drilled off central Honshu at the water depth of 945m.
A total of six wells, that is, two pilot holes, the main hole and three post survey wells, were drilled within a 100m radius of the main hole. Those wells clarified the occurrence of methane hydrate at the drilling site by wireline logging, LWD and/or coring. Four zones displaying spikes of high methane-hydrate concentration were identified based on the log responses (high resistivity, high sonic velocity, combinable magnetic resonance and porosity). FMI (Formation Micro Images) tool suggested the zones are sand rich intervals of turbidite fan deposits. The methane hydrate occurrence to fill pore spaces among grains, an advantage for resource point of view, was visually confirmed by cores from two wells.
Although the MITI Nankai Trough wells revealed the existence of methane hydrates in the pores of turbiditic sands, there remain many issues to be clarified regarding the occurrence of hydrates in the deep sea off Central Japan, including the volume and the relationship with the BSR distribution.
To collect data and information to be used in the evaluation of the resource potential of methane hydrate, a multi-well drilling campaign METI Tokai-oki to Kumano-nada was planned and carried out. Took the lead in the drilling, 2D and 3D seismic surveys targeted in the BSRs were accomplished and BSR distribution had been Tsuji 2 carefully examined and interpreted. A total of 16 drill sites at water depths of 700 to 2000 m were selected from distribution and characters of BSRs (Fig. 1). The sites were located not only with BSRs, but also without them. Some are with double BSRs and others are with high sonic velocity intervals predicted by velocity analysis.
The campaign was carried out in early 2004 applying JOIDES Resolution, which has enough experience in the drilling of methane hydrate in the ODP cruises. LWD (Logging While Drilling) wells were drilled at all of the sites, and two WL (Wireline Logging) wells, two full coring wells, and wells for spot coring of methane hydrate were drilled after the evaluation of LWD results. Methane hydrate existence was confirmed by LWD, WL and/or cores in most of the wells with BSRs. It is suggested that the occurrences of the methane hydrate are both in pore space filling in sandstone and layered or nodular form in mudstone.
The logging data as well as the core data will be evaluated and related to the 3D seismic data. The occurrences of methane hydrate and sonic velocity and seismic attributes will be compared and the study is planned to provide a methodology estimating the volume of the methane hydrate for the evaluation of resource potential.
The drilling campaign was carried out by the effort of many geologists, geophysicists, drilling engineers and many people related to the project. Especially Takatoshi Namikawa, Tetsuya Fujii, Koji Ochiai, Masao Hayashi, Masaru Nakamizu, Shoshiro Shimizu, Nobutaka Oikawa, Jun Matsushima, Tetsuo Saeki, Toshiharu Okui and Ryuta Kitamura and Masayuki Kawasaki of JOGMEC and Tomonori Mori and Takashi Sugiura of METI played important roles in preparation and operation. Japan Petroleum Exploration Co., Ltd. and Teikoku Oil Co. Ltd. jointly worked as the operating company. Discussion in MH21 consortium of Japan Methane Hydrate Exploitation Program helped the planning. Without JOIDES Resolution, we could not obtain the fruitful results. METI and JOGMEC approved the presentation of this paper.
10967-9
Appendix: A Bibliographic Guide to Fault Traps, Fault Seals and Fault-Related Fluid Flow in Sedimentary Basins
AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Rasoul Sorkhabi(Japan Oil, Gas and Metals National Corporation)
Geology & Geophysics Research Team
[Abstract] The following bibliography is a list by subject of selected journal articles and books on the role of faults in fluid flow migration and entrapment in sedimentary basins. It is a bibliographic guide for further reading and research; it is not an exhaustive bibliography. In selecting references the following criteria were considered:
1. References on fault traps, fault sealing, and fault-related fluid flow in sedimentary basins (not igneous or metamorphic terrains)
2. Full articles (not abstracts) published in English-language mainstream journals so that the references have an international accessibility
3. Under each category where a book or a special journal issue has been referenced, individual papers from that volume have not been listed for the sake of space.
4. For some categories specified with (*), only book volumes and journal special issues are given because of the broad scope of these topics.
5. The bibliography is up to March 2003 (including AAPG Bulletinfs thematic issue on Fault Seals).
The bibliographic guide has been arranged as follows:
(1) Fault Trap Structures
1.1. Faults and the Classification of Traps
1.2. Structural Styles & Closure of Fault Traps
1.3. Normal Faults, Extensional Basins, and Passive Margins
1.4. Reverse Faults, Compressional Basins, and Active Margins
1.5. Strike-Slip Faults and Wrench Basins
1.6. Faults of Salt Tectonics
1.7. Faults of Inversion Tectonics and Inverted Basins
1.8. Subsurface Mapping of Faults
1.9. Faults on Seismic Images
1.10. Construction of Fault Surface Geometry and Fault Juxtaposition
(2) Fault Sealing Processes
2.1. Sealing Mechanisms: General Aspects
2.2. Fault Rocks and Fault Sealing Processes: General Aspects
2.3. Cataclastic Rocks
2.4. Shale Smear in Clastic Sequences
2.5. Deformation Bands in Porous Sandstone
2.6. Pressure Solution Seals
2.7. Mineral Veins and Crack Seals Associated with Faulting
2.7. Fault-related Diagenesis and Fluid-Rock Interactions in Fault Zones
(3) Fault-Related Fluid Flow
3.1. Fluid Flow in Rocks
3.2. Fault-Related Fluid Flow: Field Studies
3.3. Fluid Flow and Natural Seismicity
3.4. Fluid Flow and Induced Seismicity in Petroleum Basins
3.5. Structural Controls on Petroleum Seepage
(4) Petrophysical Properties of Faults
4.1. Empirical Measurements
4.2. Experimental Measurements
4.3. Numerical Simulation
(5) Analysis of Fault Stress, Stability and Failure
5.1. Rock Mechanics, Rock Stress, and Fault Mechanics
5.2. Borehole Technologies for Fault Stress Measurements
5.3. Field Studies
10967-8
Geochemical Signatures of Fluid Flow in Thrust Sheets:
Fluid-Inclusion and Stable Isotope Studies of Calcite Veins in Western Wyoming
AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Rasoul Sorkhabi(Japan Oil, Gas and Metals National Corporation)
Geology & Geophysics Research Team
[Abstract] The fold-and-thrust belt of western Wyoming consists of a series of thrust sheets formed in the Cretaceous-Paleocene during the Sevier-Laramide orogenies. The stratigraphic succession ranges from the Cambrian through the Eocene, and the thrust packages have been transported for several kilometers in a thin-skinned (basement-detached) tectonic regime. The major thrust faults in the region are east verging, and become younger from the west toward the east with a decrease in displacement amount but an increase in thrust velocity. The thrust zones are associated with mineral veins of various styles, including those in fractured limestones, conjugate veins, en echelon veins, and fracture-fills of fault breccias. Calcite veins provide geochemical signatures of fluid flow in the thrust zones. Fluid inclusion data from the calcite veins demonstrate the flow of not only various generations of brine but also liquid hydrocarbons. Aqueous inclusions yield homogenization temperatures (minimum inclusion temperatures) of three populations: 110-125 ℃, 130-140 ℃, and 158-163 ℃ with brines of various salinities, indicative of both freshwater and highly saline water. Petroleum inclusions record relatively lower homogenization temperatures (>100 ℃) compared to brines. Stable isotope analyses of host limestone rocks and calcite veins clearly indicate meteoric water flushing through thrust zones, thus altering the oxygen chemistry of host rock. δ13C values for host limestone rocks and calcite veins were found to be very similar indicating the precipitation of the same carbonaceous matter from host rock in the vein. In contrast, δ18O values are quite different for host limestone rocks and calcite veins indicating distinct origin and heterogeneous nature of brines. Micro-permeability measurements of calcite veins in a fault breccia as well as a calcite-cemented sandstone yielded similar range of gas permeability between host rock fragments and calcite veins.
10967-7
Fault Zone Architecture and Permeability Distribution in the Neogene Clastics of Northern Sarawak (Miri Airport Road Outcrop), Malaysia
AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Rasoul Sorkhabi, Shutaro Hasegawa(Japan Oil, Gas and Metals National Corporation)
Geology & Geophysics Research Team
[Abstract] The Miri Airport Road outcrop in Miri, Sarawak, has exposed a weakly-consolidate sandstone-mudstone sequence of Miocene age in the form of a gentle anticline cut by a series of normal faults. An outcrop study of the normal faults shows that fault zones in porous sandstones are characterized by a combination of shale smear and anastomosing deformation bands. The continuity of shale smear on fault offset was observed as having a "shale smear factor" (fault throw divided by shale layer thickness) of at least 5. Deformation bands occur as solitary planar structures in host sandstone away from fault zone but increase remarkably in density and linkage toward fault slip plane, possibly indicating that the faulting evolves from individual bands to a high strain zone characterized by anastomosing deformation bands and culminating in fault slip plane. Gas permeability measurements show that individual deformation bands have an order of magnitude lower permeability than the nearby sandstone matrix, and that the permeability of fault zone defined by anastomosing deformation bands is the lowest across a fault traverse. It was found that sandstone matrix in the fault zone has lower permeability than individual deformation bands outside the fault zone indicating that fault zone as a whole undergoes tectonic compaction and porosity collapse. The development of major normal faults was also accompanied by reactivation of bedding-perpendicular joints as small-displacement simple-shear faults in between the major faults.
10967-6
Development of Synthetic Layer Dip Adjacent to Normal Faults
AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
David A. Ferrill(Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute), Alan P. Morris(University of Texas), Darrell W. Sims, Deborah J. Waiting(Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute), Shutaro Hasegawa(Japan Oil, Gas and Metals National Corporation)
Geology & Geophysics Research Team
[Abstract] Field analyses of normal faulting illustrate that synthetic layer dip associated with normal faults is a common feature of extensional fault systems. These synthetic dip panels are developed where layers on upthrown, downthrown, or both sides of a normal fault dip toward the downthrown side of the fault. Synthetic dip panels adjacent to normal faults should be expected at some scale in all normal fault systems. In addition to faults developed in strata with a regional dip, five fault-related mechanisms for the development of synthetic dip are: faulted monocline (fault tip-line folding), antilistric fault bend, distributed shear, shear in relay zone of vertically and/or laterally segmented faults, and fault block impingement and lateral contraction. Development of synthetic dip accommodates a component of throw by tilting or folding, thereby reducing the offset of true displacement on the related normal faults. Fault block deformation is strongly dependent on the mechanisms that produce synthetic dip panels, and may influence fault zone and block permeability. Depending on stratigraphic and structural relationships, synthetic dip panels can produce downthrown closure for hydrocarbon trapping, provide fluid migration and/or production communication pathways across faults, or produce barriers to fluid communication across faults
10967-5
Analogue Models of Faults Associated with Salt Doming and Wrenching: Application to offshore UAE
AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Yasuhiro Yamada(JAPEX Research Center), Hitoshi Okamura(Japan Oil, Gas and Metals National Corporation), Yoshihiko Tamura(JODCO), Futoshi Tsuneyama(Japan Oil, Gas and Metals National Corporation)
Geology & Geophysics Research Team
[Abstract] Regional stress has a significant impact on fault development during the formation of salt dome structures. In order to examine such effects of wrenching, we conducted a series of analogue experiments of up-doming using dry granular materials and observed the deformation on the top free surface. The experiments included three deformation styles: 1) up-doming followed by wrenching, 2) simultaneous up-doming and wrenching, and 3) wrenching followed by up-doming. In the first series of the experiments, the faults produced by simple up-doming were overprinted by two strike slip fault systems generated by the subsequent wrenching. The second series of experiments with the configuration of simultaneous up-doming and wrenching generated normal faults in a direction perpendicular to relative extension by the wrench. In the third series of experiments, the Riedel and anti-Riedel shear faults formed by wrenching were deformed by the subsequent up-doming, and were overprinted by the faults related to the up-doming.
These experimental results are applied to the fault systems observed above dome structures in the UAE region, where extensive faults in the northwest-southeast direction have developed. By analogy, these faults were probably formed during an up-doming and simultaneous wrenching. The direction of simple shear inferred from a comparison of real faults and experimental results suggests that dextral wrenching caused by the Oman Stress regime during the Late Cretaceous affected the region at the time of the up-doming.
10967-4 Extensional Fault System Evolution and Reservoir Connectivity AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Darrell W. Sims(Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute), Alan P. Morris(University of Texas), David A. Ferrill(Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute), Rasoul Sorkhabi(Japan Oil, Gas and Metals National Corporation) Geology & Geophysics Research Team
[Abstract] Sandbox analog modeling experiments provide new insights into the effects of fault geometry on reservoir connectivity. During progressive distributed extension, three phases of fault system evolution are apparent. In Phase I, geometrically simple faults nucleate rapidly at a large number of sites throughout the deforming region. This is followed by Phase II in which faults link and increase in trace length. Phase III is characterized by a quasi steady-state nucleation and linkage of faults. Reservoir connectivity has many components; here we focus on fault-controlled connectivity, which can be viewed from two complementary perspectives: rock mass connectivity (continuity of rock between and around faults), and fault network connectivity. Which of these perspectives is adopted depends upon whether faults cutting the reservoir act as barriers to flow (e.g., in highly porous sandstone reservoirs) or conduits for flow (e.g., in fractured carbonate reservoirs). We use two measures of fault-controlled connectivity: (i) a fault density measure derived from the number of intersections between faults and potential flowpaths, and (ii) the ratio of number of fault tips to number of faults. Taken together, these characteristics convey both the short-term transmissivity characteristics and the ultimate leakiness of the reservoir.
10967-3 Fault Seal Analysis Applied to the Erawan Gas-Condensate Field in the Gulf of Thailand AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Tokio Kachi, Hideki Yamada, Kiyoshi Yasuhara(Mitsui Oil Exploration Company), Masamichi Fujimoto, Shutaro Hasegawa, Shoji Iwanaga, Rasoul Sorkhabi(Japan Oil, Gas and Metals National Corporation) Geology & Geophysics Research Team
[Abstract] The Erawan field in the Gulf of Thailand is characterized by a series of east- and west-dipping normal faults displacing the Miocene clastic reservoirs. The fault seal capacity of these faults was assessed using sand-shale juxtaposition diagrams, clay smear parameters, and fault seal failure probability (based on in-situ stress conditions). For this study, five east-dipping faults in the Erawan North Platform area were selected (faults E-16, E-17, E-18, E-20, and E-27). Several deviated wells have been drilled through the footwall blocks of these faults. Low values of Shale Smear Factor (SSF<6) and high values of Clay Content Ratio (CCR>30%) of four of the faults suggest that fault seal along their planes. In contrast to these four faults, fault E-27 appears to act as an across-fault conduit for some intervals and seal in others. Intervals without trapped hydrocarbons have higher SSF values suggesting that the fault leaks locally. These five faults trap 15 gas pay zones. Eight of the pay zones have sand-shale juxtaposition across the faults which may explain 8 of the 15 accumulations. Clay smear parameters can account for all 15 accumulations. Fault seal failure probability (FSFP) was derived fro one of these faults (E-16) by integrating the CCR values and the probability of fault slip tendency and fault dilation tendency under the current stress regime in the Erawan field. Low FSFP values indicate that the fault seals do not appear to have been breached given the in-situ stress field acting upon the normal fault.
10967-2 Fault Seal Analysis in the Temana Field, Offshore Sarawak, Malaysia AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Shutaro Hasegawa, Rasoul Sorkhabi, Shoji Iwanaga, Naofumi Sakuyama(Japan Oil, Gas and Metals National Corporation), Othman Ali Mahmud(PETRONAS) Geology & Geophysics Research Team
[Abstract] The Temana field is located on a structural high in the Balingian province, offshore Sarawak, Malaysia. Fault sealing assessment of a normal fault in the Tertiary clastic rocks of the Temana field was carried out using the shale smear parameters. Shale Smear Factor (SSF) values of <6 and Clay Content Ratio (CCR) of >30% on the fault surface indicate across-fault sealing of the reservoir rocks. The fault sealing appears to be efficient enough to support the hydrocarbon columns filled up to the structural spillpoints of reservoirs. Fault rock permeability calculated from the available calibrations of clay content-permeability relationship show lower permeabilities of <0.3 mD. Taking the Temana fault as a case in point, new approaches on the estimation of hydrocarbon column height from across-fault pressure differences, and fault rock permeability probability (based on integration of clay content, fault displacement and depth factors) are discussed.
10967-1 The Place of Faults in Petroleum Traps AAPG Memoir 85 "Faults, Fluid Flow, and Petroleum Traps"
2005
Rasoul Sorkhabi, Yoshihiro Tsuji(Japan Oil, Gas and Metals National Corporation) Geology & Geophysics Research Team
[Abstract] Ever since Frederick Clapp included fault structures as significant petroleum traps in the 1910s, the myriad role of faults in petroleum migration and accumulation in sedimentary basins has drawn increasing attention. Fault analyses in petroleum traps have grown along two distinct and successive lines of thought: (1) fault closures, and (2) fault-rock seals. Through most of the last century, geometric closure of fault traps and reservoir-seal juxtaposition by faults were the focus of research and industrial application; as structural geology developed quantitative methods for geometric and kinematic analyses of sedimentary basins, and plate tectonics offered a unified tool to correlate faults and basins on the basis of the nature of plate boundaries as stress engines. Over the last two decades, compartmentalization of reservoirs by fault seals has been intensively investigated as 3D seismic images better resolve fault structures. Geometric characterization of fault architecture, identification of various sealing processes in fault zones, and quantitative appraisal of petrophysical properties of fault rocks have been significant advances of the recent decades.
10965 Mapping a fracture network using wide-azimuthal Ocean Bottom Cable seismic data The Leading Edge
2005/1
Mu Luo, Isao Takahashi, Mamoru Takanashi(Japan Oil, Gas and Metals National Corporation), Yoshihiko Tamura(Japan Oil Development Co., Ltd. ) Research Project Team on Carbonate Reservoir
[Abstract] For enhanced oil and gas production from fractured reservoirs, there is an increasing need to image fracture systems through the study of wide-azimuthal surface P-wave seismic data. There is an established understanding that reservoir complexity could be diagnosed through seismic anisotropy studies. One of the technical challenges remaining is to maximally exploit seismic attribute sensitivities to improve the mapping of the spatial distribution of subsurface fractures. In the paper, we present a case study of mapping a possible fracture network using wide-azimuthal Ocean Bottom Cable (OBC) seismic data recorded over a Middle East offshore production field. Results shown in the paper demonstrate the potential for obtaining detailed fracture information through seismic studies.
10964 Subsurface occurrence and distribution of natural gas hydrate at the Mallik site: Implications for the future energy potential in the Nankai Trough ICDP Conference (International Continental Drilling Program Conference)
2005/3/29
Takashi Uchida(JAPEX Research Center) Methane Hydrate Research Project Team
[Abstract] Gas hydrates are ice-like clathrate solids made of water molecules containing various gas molecules in their cages. The geological evaluations have suggested worldwide methane contents in gas hydrate beneath deep sea floors as well as permafrost-related zones to about twice the total resources of conventional and unconventional hydrocarbon. Occurrences of subsurface gas hydrate in deep marine and permafrost-associated environments are in the pressure-temperature stability field typically around 10℃, or 10 MPa. Scientific and economic interests have been increasing in gas hydrate, and new research appraisals on gas hydrate are presented relevant to a new energy resource, climate, and geohazard research as a potential greenhouse gas.
In 2002 Mallik wells were drilled in the Canadian Arctic with support from the Mallik Gas Hydrate Production Research Well Program, and a substantially expanded science program was enabled through the ICDP. The scientific results clarified the characteristics of gas hydrate-dominant layers at depths from 890 to 1110 m beneath the permafrost zone. Continuous downhole well log data, anomalies of chloride contents in pore waters, core temperature depression due to endothermic decomposition of gas hydrate as well as visible gas hydrates have confirmed the highly saturated pore-space hydrate as intergranular pore filling within sandy layers. It should be remarked that their saturations in pore volume are evaluated up to 80%, and that muddy sediments scarcely contain gas hydrate.
The Nankai Trough runs along the Japanese Island, where forearc basins and accretionary prisms developed extensively and BSRs (bottom simulating reflectors) have been recognized widely. The multiple wells drilled by the Japanese government METI in 2000 and 2004 also revealed the presence of pore-space hydrate filling intergranular pore of sandy layers. It is suggested that the distribution of a porous and coarser-grained sandy sediments is one of the most important factors to control the occurrence of gas hydrates, as well as physicochemical conditions.
There are many similar features in appearance and characteristics of gas hydrate between the Mallik and Nankai Trough areas with observations of well-interconnected and highly saturated pore-space hydrate. A key goal for the Japanese scientists in the Mallik programs is to undertake scientific and engineering studies in the known terrestrial gas hydrate occurrence and apply those results to the major research program on gas hydrate on the relevance to the future production testing in the Nankai Trough.
10960 Pore Space Reconstruction using Multiple-Point Statistic Journal of Petroleum Science and Engineering
2005/2/15
Hiroshi Okabe(Japan Oil, Gas and Metals National Corporation, Imperial College London), Martin J. Blunt(Imperial College London) Petroleum Engineering Research Team
[Abstract] The reconstruction of porous media is of great interest in a wide variety of fields, including earth science and engineering, biology, and medicine. To predict multiphase flow through geologically realistic porous media it is necessary to have a three dimensional (3D) representation of the pore space. Multiple-point statistics were used, based on two-dimensional (2D) thin sections as training images, to generate 3D pore space representations. The method was borrowed from geostatistical techniques that use pixel-based representations to reproduce large-scale patterns. Thin-section images can provide multiple-point statistics, which describe the statistical relation between multiple spatial locations. Assuming that the medium is isotropic, a 3D image can be generated that preserves typical patterns of the void space seen in the thin sections. The method is tested on Fontainebleau and Berea sandstones for which 3D images from micro-CT scanning are available. The use of multiple-point statistics predicts long-range connectivity of the structures (measured by local percolation probability) better than standard two-point statistics methods. The selection of multiple-point statistics is a key issue and is discussed in detail.
10956 Good design and operation of MEOR field test based on the biotechnological approaches 13th International Oil, Gas and Petrochemical Congress
2005/1/26
Kazuhiro Fujiwara(CHUGAI TECHNOS Co.), Kenji Ono, Nintoku Yazawa(Japan Oil, Gas and Metals National Corporation), Heiji Enomoto(Tohoku University), Cheng Xie Hong(Jilin Oilfield Company, China) Petroleum Engineering Research Team
[Abstract] Through an international collaborative research program between Technology and Research Center of Japan Oil, Gas and Metals Corporation (JOGMEC) and PetroChina Jilin Oilfield Company, the effectiveness of biotechnological approaches for MEOR was ascertained. The objectives of this research were twofold: the collection of valuable data proving MEORfs effects, and the development of fundamental technologies for collection of microbial data and for technical breakthrough in MEOR.
Firstly, we developed a biotechnological tool, that is, PCR-RFLP method to estimate the behavior of microbes which had an ability to propagate using molasses in the reservoir and could struggle for existence with the target microbe. Consequently, scientific knowledge of the microbes inhabiting in the reservoir rock and materials relating to the MEOR process such as ground water, molasses, and reservoir brine were collected through both laboratory cultivation tests and molasses injection tests in the field.
Secondly, a microbe CJF-002 to be injected in the reservoir which had an ability to produce insoluble polymer was screened to plug highly permeable paths. In addition, the combinational method with Direct-PCR was also developed for monitoring the target microbe(s) among many others.
Finally, continuous injection tests with CJF-002 were conducted to demonstrate the fundamental breakthroughs in MEOR technology and the real state of MEOR as well.
As conclusions, it was demonstrated that biotechnological approaches can contribute to promote the prevalence of MEOR.
10955 Modeling and EOR Performance Predictions of a Fractured Carbonate Reservoir 13th International Oil, Gas and Petrochemical Congress
2005/1/26
Kenji Ono, Yoshihiro Tsuji(Japan Oil, Gas and Metals National Corporation), Maghsood Abbaszadeh(Innovative Petrotech Solutions Inc.), David H. Zamora Guerrero(PEMEX) Petroleum Engineering Research Team
[Abstract] A joint study was conducted by PEMEX and JOGMEC (former JNOC) to develop integrated technologies for evaluating and revitalizing a compartmentalized naturally fractured carbonate reservoir. A new stratigraphic layering has been established based on enhanced log responses obtained from waveform frequency analysis combined with core/thin section observations. Faults and fractures are found to have major impacts on reservoir properties; thus a comprehensive effort is made to characterize them. The lineament analysis on topographic contours and aerial photographs, and structural maps indicate NW-SE trend of faults/fractures in the region. Statistical data on fracture spacing and occurrences are obtained from image logs and outcrop data. Fractal analysis was applied to obtain areal fracture density and fracture distribution patterns in the field. The pressure performance as well as salinity of produced water differ among blocks in the field. The dynamic data interpretation suggests possible barriers in the orthogonal direction to the major trend. The double porosity phenomena and/or the presence of conductive faults were suggested for some wells from well test analyses. A 3D geological model for flow simulation was constructed, and the simulation model was calibrated to reservoir production data by history matching. Several EOR gas injection cases were studied to provide guidelines for subsequent field development scenarios.
10954 MEOR/MIOR Field Applications - Biotechnological Know-How is Key to the Success 13th International Oil, Gas and Petrochemical Congress
2005/1/26
Kenji Ono(Japan Oil, Gas and Metals National Corporation), Kazuhiro Fujiwara(CHUGAI TECHNOS Co.), Heiji Enomoto(Tohoku University), Cheng Xie Hong(Jilin Oilfield Company, China) Petroleum Engineering Research Team
[Abstract] Several different microbes have been applied to a shallow sandstone reservoir in collaboration with Jilin Oilfield Company. The reservoir has been waterflooded for more than 20 years and watercut was 80-90%. TRC-322, Enterobacter, and some other microbes, which produce CO2, acid and soluble polymer, were firstly applied to the production wells. Microbes and nutrients were continuously injected after the huff-n-puff operation. Some sixty percent of the wells showed increase in oil cut, effectiveness, however, was relatively limited. A different Enterobacter, CJF-002 produces insoluble polymer was searched and identified in the oilfield. Different approaches, a huff-n-puff at production wells and a microbial treatment at injection wells was adopted. The water cut in production wells were dramatically reduced shortly after the microbial treatment at injection wells. Oil production in the test area increased by more than double in volume and effect of plugging high permeable zones was continued longer than half a year. During these treatments, monitoring and evaluating properly the in-situ growth of the target microbes by CFU + PCR method and the metabolic activities by HPLC are quite important to identify and evaluate the mechanism of the microbial process. Process modification and adjustment to the particular environment based on the biotechnological know-how is key to the successful field applications of MIOR/MEOR.
10952 Hydrogen production with steam reforming of dimethy‚Œ ether 1st International Fuel Cell Expo 2005, Academic Forum
2005/1/19
Takeishi Kaoru(Shizuoka University) Research Project Team on Emerging Gas Technologies
[Abstract] Dimethyl ether (DME) is expected as one of clean fuels, and DME is one of substitutes of diesel fuel and LPG. Infrastructures of LPG will be able to use for DME infrastructures.
We studied the hydrogen production with steam reforming of DME, for fuel cells.
Large quantities of H2 and CO2 were produced from DME and water using alumina catalysts prepared by a sol-gel method, especially copper alumina catalysts. Other metal alumina catalysts prepared by the sol-gel method produced H2 and CO2, but also produced large quantities of carbon monoxide. Our studies showed that copper is the best metal for the production of H2 while producing less CO. ƒÁ-Alumina for DME hydrolysis into methanol, and active metals such as copper for methanol steam reforming to H2 and CO2 are mixed and distributed closely on the surfaces of catalysts prepared by the sol-gel method. Therefore, sol-gel catalysts produce H2 and CO2 well from DME.
10948 Prediction of Permeability for Porous Media Reconstructed using Multiple-Point Statistics Physical Review E
2004/12/23
Hiroshi Okabe(Japan Oil, Gas and Metals National Corporation, Imperial College London), Martin J. Blunt(Imperial College London) Petroleum Engineering Research Team
[Abstract] To predict multiphase flow through geologically realistic porous media, it is necessary to have a three-dimensional (3D) representation of the pore space. We use multiple-point statistics based on two-dimensional (2D) thin-sections as training images to generate geologically realistic 3D pore space representations. Thin-section images can provide multiple-point statistics, which describe the statistical relation between multiple spatial locations and use the probability of occurrence of particular patterns. Assuming that the medium is isotropic, a 3D image can be generated that preserves typical patterns of the void space seen in the thin-sections. The method is tested on Berea sandstone for which a 3D image from micro-CT scanning is available and shows that the use of multiple-point statistics allows the long-range connectivity of the structure to be preserved, in contrast to two-point statistics methods that tend to underestimate the connectivity. Furthermore, a high-resolution 2D thin-section image of a carbonate reservoir rock is used to reconstruct 3D structures by the proposed method. The permeabilities of the statistical images are computed using the lattice-Boltzmann method (LBM). The results are similar to the measured values, to the permeability directly computed on the micro-CT image for Berea and to predictions using analysis of the 2D images and the effective medium approximation.
10946 Concentration of Natural Gas Hydrate Beneath the Permafrost Zone: Implications for Geochemical and Hydrologic Investigations AGU (American Geophysical Union)
2004/12/13
Amane Waseda(Japan Petroleum Exploration Co., Ltd.), Takatoshi Namikawa(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] Gas hydrates are ice-like solids that have cages made of water molecules containing various gas molecules. The geological evaluations have suggested the worldwide methane content of gas hydrate beneath deep sea floors along continental margins as well as permafrost-related zones to about twice the total reserves of conventional and unconventional hydrocarbon. Scientific and economic interests are increasing in gas hydrate as a new energy resource and a potential greenhouse gas. In 1998 and 2002 Mallik wells were drilled in the Canadian Arctic that clarified the characteristics of gas hydrate-dominant layers at depths from 890 to 1110 m beneath the permafrost zone. Continuous downhole well log data, anomalies of chloride contents in extracted pore waters, core temperature depression, core observations as well as visible gas hydrates have confirmed the presence of highly saturated pore-space hydrate as intergranular pore filling within sandy layers, whose saturations are higher than 70 % in pore volume. Muddy sediments which separate the main gas hydrate-bearing layers scarcely contain gas hydrate. The Nankai Trough runs along the Japanese Island, where forearc basins and accretionary prisms developed extensively and BSRs (bottom simulating reflectors) have been recognized widely. The METI Nankai Trough wells in 2000 also revealed the presence of pore-space hydrate filling intergranular pore of sandy layers. It is remarked that there are many similar features in appearance and characteristics between the Mallik and Nankai Trough areas with observations of well-interconnected and highly saturated pore-space hydrate. It is necessary for evaluating subsurface fluid flow behaviors to know both porosity and permeability of gas hydrate-bearing sandy sediments, and measurements of water permeability for them indicate that highly saturated sands may have permeability of a few milli-darcies. Subsequent analyses in sedimentology and geochemistry performed on gas hydrate-bearing sands revealed important geologic and sedimentologic controls on the formation and concentration of gas hydrate. It is suggested that the distribution of a porous and coarser-grained sandy sediments is one of the most important factors to control the occurrence of gas hydrates, as well as physicochemical conditions.
10944 Multidisciplinary Approach for Borehole Instability Problems in a Shale formation 3rd Asian Rock Mechanics Symposium
2004/11/29
Koji Yamamoto(Japan Oil, Gas and Metals National Corporation) Petroleum Engineering Research Team
[Abstract] Shale instability problem during drilling operation are complex phenomena that involve many mechanical, chemical, and operational factors. In a collaborative study on this costly problem for the oil industry, integrated researches of various scale of instability mechanism were carried out to determine the nature of shale instability problems in deep petroleum wells. In this paper, an example of shale trouble and our approach for it are presented. The characteristic nature of shale such as chemical activity, anisotropy, fissured nature fully considered. The approach to the problem and modeling concepts are described. The results suggest the limitation of conventional elastic approaches.
10943 Estimation of sonic attenuation properties of methane hydrate-bearing sediments from the Nankai Trough exploratory well off Tokai, central Japan The 7th SEGJ International Symposium
2004/11/26
Jun Matsushima(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] Full waveform logs from the Nankai Trough exploratory well off central Japan are used to estimate both compressional and shear attenuation in methane hydrate (MH) bearing sediments. Attenuation estimation is based on a median frequency shift to the amplitude spectrum of the recorded waveforms. This paper is concerned with the estimation of attenuation at sonic frequencies 10-20 kHz for compressional waves and 500-1500 Hz for shear waves. The high attenuation of the compressional waveforms and high attenuation of the shear waveforms correlate well with the presence of methane hydrate inferred from the resistivity log. On the other hand, we observed the high attenuation of the compressional waveforms and low attenuation of the shear waveforms below the methane hydrate stability zone. This can be explained by the presence of partially gas-saturated sediments. The shear attenuation may therefore be directly related to MH because the compressional attenuation is strongly affected by the presence of gas. The ratio of compressional to shear attenuation is found to be a more sensitive indicator of the presence of gas than is the corresponding velocity ratio. We concluded that sonic attenuation from both monopole and dipole waveforms should give new insight to characterize methane hydrate bearing sediments and gas-saturated sediments.
10945 Phylogenic analysis of Methanogens in the gas wells Japanese Society of Microbial Ecology
2004/11/21-23
Hanako Mochimaru(National Institute of Advanced Industrial Science and Technology, AISTEUniversity of Tsukuba), Hiroyuki Imachi(Nagaoka University of Technology), Yuji Sekiguchi(National Institute of Advanced Industrial Science and Technology, AIST), Aya Amaishi(Taisei Corporation), Toshihiro Hoaki(Taisei Corporation), Hiroo Uchiyama(University of Tsukuba), Yoichi Kamagata(National Institute of Advanced Industrial Science and Technology, AIST) Methane Hydrate Research Project Team
[Abstract] We studied diversity of methanogens in the subsurface ecosystems in Niigata and Mobara natural gas fields to figure out the relation between methanogenic populations and methane production. Our studies indicate that there are a number of methanogenic species in the samples based on molecular analysis. We will show these data and the traits of methanogens isolated from these ecosystems.
10938 Application of Genetic Algorithm to history matching for core flooding 2004 SPE Asia Pacific Oil & Gas Conference and Exhibition (APOGCE)
2004/10/20
Noriyuki Tokuda, Shunya Takahashi(Japan Oil, Gas and Metals National Corporation), Makoto Watanabe(Japan Oil Development), Takeshi Kurose(CRC Solutions) Research Project Team on Carbonate Reservoir
[Abstract] Recently it has become a common practice to construct 3D coreflooding simulation model to interpret water displacement experiments conducted under X-ray CT scanning. The unknown grid block parameters i.e. kro/krw and Pc curves are required to be optimized to get reasonable matching with experimental data such as changes of grid block water saturation. In order to evaluate the matching process efficiently a new automated history-matching program has been developed. This program applies Genetic Algorithm to optimize several coefficients for normalized kro/krw and Pc curves for each litho-facies. Several blind tests were carried out on hypothetical coreflooding models by changing the conditions of velocity and wettability to investigate the degree of accuracy and limitation of the program. The result of the reproducibility of the relative permeabilities was excellent for both water-wet and oil-wet cases regardless the velocity of coreflooding. On the other hand, the degree of reproducibility was not necessarily satisfactory for capillary pressure curves especially in high velocity case. Sensitivity of the controlling parameter in Genetic Algorithm such as crossover rate and mutation ratio was also investigated. The suitable values are estimated, though no simple trend was found. The program was finally applied to the interpretation of actual water displacement tests on oil-wet carbonate cores. The program successfully gave a reasonable set of kro/krw and Pc curves for each litho-facies and demonstrated its capability of grid block parameter optimization.
10937 New GTL Process -Best Candidate for Reduction of CO2 in Natural Gas Utilization-(SPE 88628) 2004 SPE Asia Pacific Oil & Gas Conference and Exhibition (APOGCE)
2004/10/20
Yoshifumi Suehiro, Masaru Ihara, Kazuhito Katakura(Japan Oil, Gas and Metals National Corporation), Arata Nakamura, Atsushi Sakamoto(INPEX Corporation), Kenichi Kawazuishi, Ryuichiro Kajiyama(CHIYODA Corporation), Kenichiro Fujimoto, Yasuhiro Ohnishi(Nippon Steel Corporation), Hideo Okado(Japan Petroleum Exploration Corporation, Ltd.), Toshio Shimizu(COSMO Oil Corporation, Ltd.) Research Project Team on Emerging Gas Technologies
[Abstract] Japan Oil, Gas and Metals National Corporation (JOGMEC), which is a former Japan National Oil Corporation (JNOC), has been developing natural gas to liquids (GTL) conversion technology since the year of 1998 in collaboration with five private Japanese companies, namely; JAPEX Co. Ltd., Chiyoda Corp., COSMO Oil Co. Ltd., Nippon Steel Corp., and INPEX Corp. Our new GTL process is particularly effective when it is applied to natural gas feed stock containing 20-40mol% of CO2. It does not require the three expensive items; (1) an oxygen supply plant, (2) a unit for CO2 separation from natural gas, and (3) a H2 separation unit to optimize gas composition. The reduction of these facilities, which are indispensable to the conventional GTL process, would results in less CAPEX and OPEX. For our new GTL process, the most preferable CO2 content in feed natural gas is around 30mol%. Therefore, in case that the CO2 content is less than 30mol%, some amount of CO2 can be supplied from other CO2 sources, such as flare gas, associated gas, remaining CO2 of EOR and exhausted gas from oil refinery and LNG plant. This paper aims to present applications of our new GTL process to enable an economic exploitation of gas reserves in South East Asia and Australia, by taking into account the operation results of the Yufutsu GTL pilot plant of 7BPSD located at Tomakomai city in Hokkaido of Japan, and the study results of process simulation and the economics. We present an attractive combination scheme for our new GTL process with LNG plant by utilizing CO2 exhausted from LNG plant. It reduces initial projectfs investment compared with a stand-alone GTL plant located in South East Asia and Australia, where infrastructure of an LNG plant can be for common use with our GTL plant.
10935 A Turbine Flow Meter for Multiphase Flow(SPE 88741) The 11th Abu Dhabi international Petroleum Exhibition and Conference
2004/10/13
Zhenyan Li, Hirokazu Kitami, Hiraku Kawaoto(Oval Corporation), Tomoko Watanabe(Japan Oil, Gas and Metals National Corporation) Research Project Team on Carbonate Reservoir
[Abstract] This paper introduces a new concept and the test result of a multiphase flow meter (MPFM), which JOGMEC (Old JNOC) and OVAL Corporation have developed based on a turbine type flow meter to measure the multiphase flow rate of individual phases in oil, water and gas production lines without the need for separation or complex sensor technologies (1)(2). It is expected that the MPFM should bring a significant cost-down and improved operability and maintainability, compared with commercially available a multiphase flow meter in terms of nuclear-absorption type density measuring. We had adopted integral calculus method and established a mathematics model. In addition, we have examined the characteristics of the MPFM using a number of liquids with different viscosities (1-20mPas). The test result shows that the volumetric flow rate of each phase are possibly measured with an uncertainty within }10% of full scale while the water cut varies from 0% to 100%, and the gas void fraction varies from 30 to 90%. To confirm the MPFM reliability, MPFM monitoring was done for one year in an oil reservoir with water flooding in the wellhead platforms (WHPTs) in the Middle East. The MPFM measurement system can obtain enough accuracy to measure flow rates in each phase.
10934 Reservoir Characterization Study of the Cuitlahuac Gas Field in the Burgos Basin, Northern Mexico SEG 2004 International Exposition & 74th Annual Meeting
2004/10/12
Shinichi Matsuzawa, Yusaku Konishi(Japan Oil, Gas and Metals National Corporation), Tomohisa Nishizuka(Idemitsu Petroleum Norge A.S.), Arturo Perez Aldana, Efrain Mendez Hernandez, Jose Alberto Santana Fernandez(PEMEX Exploration and Production) Overseas Survey Team
[Abstract] A recent trend in reservoir studies is the integration of petrophysical, geological and geophysical information in high-resolution reservoir models. Success in integrated reservoir characterization depends on identifying seismic and petrophysical attributes that are well correlated to the properties being modeled e.g., lithofacies, porosity and fluid type. This study employed integrated petrophysical analysis, well-based rock property study, acoustic and elastic inversions, AVO modeling and attribute generation to characterize Oligocene gas reservoirs in the Cuitlahuac Gas Field in the Burgos Basin of northern Mexico. Cuitlahuac Gas Field has produced over 320 Bcf since its discovery in 1972. Current daily production is 28 MMcfd. Production is from thin-bedded Tertiary fluvio-deltaic clastics with complex reservoir geometry. Of nine well-based seismic attributes generated from petrophysical logs (Poisson's Ratio, Acoustic Impedance, Shear Impedance, Lambda, Mu, Bulk Modulus, Lambda-Rho, Mu-Rho and Vp/Vs), acoustic impedance (AI) most effectively discriminates sandstone from shale - but only in the shallower section. Amplitude versus offset (AVO) analysis shows Class I response in the shallower section and Class II response in the deeper section. On the other hand, fluid substitution shows that Mu-Rho and Lambda-Rho are good discriminators for both lithology and fluid type. To capture detail in the thin gas reservoirs, high-resolution stochastic inversion was performed on the 3D seismic volume. The resulting acoustic and shear impedance volumes show good correlation with well log data. The attributes Lambda-Rho and Mu-Rho were calculated from the acoustic impedance (Ip) and shear impedance (Is) volumes. The seismic-derived Lambda-Rho and fluid type at each well were integrated using sequential indicator simulation with collocated cokriging to obtain a reservoir model.
10933 Attenuation measurements from sonic full waveform logs in gas hydrate bearing sediments SEG 2004 International Exposition & 74th Annual Meeting
2004/10/10-15
Jun Matsushima(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] Full waveform logs from the Nankai Trough off central Japan are used to estimate both compressional and shear attenuation in gas hydrate bearing sediments. The high attenuation of the compressional waveforms and high attenuation of the shear waveforms correlate well with the presence of gas hydrate inferred from the resistivity log. On the other hand, we observed the high attenuation of the compressional waveforms and low attenuation of the shear waveforms below the gas hydrate stability zone. This can be explained by the presence of partially gas-saturated sediments. We concluded that sonic attenuation from both monopole and dipole waveforms should give new insight to characterize gas hydrate bearing sediments and gassaturated sediments.
10932 Predicting Permeability through 3D Pore-Space Images Reconstructed Using Multiple-Point Statistics SCA 2004 International Symposium
2004/10/9
Hiroshi Okabe(Japan Oil, Gas and Metals National CorporationI, imperial College London), Martin J. Blunt (Imperial College London) Petroleum Engineering Research Team
[Abstract] Pore-scale network modeling can predict multiphase flow properties with arbitrary wetting conditions if the network represents the geology of the sample accurately. Such pore-scale modeling uses topologically disordered networks that realistically represent the pore structure. To generate the network it is first necessary to have a three-dimensional voxel-based pore-space representation that is constructed by either a direct imaging technique such as micro-CT scanning, stochastic methods, or object-based approaches. Micro-CT scanning is the most promising among these three approaches since it is the most direct. However, its resolution - a few microns - means that for many rocks, particularly carbonates, significant porosity cannot be imaged. Furthermore, alternative approaches, such as reconstruction through simulating the geological processes by which the rock was formed, such as sedimentation and diagenesis, may be problematic for many materials whose depositional and diagenetic history is uncertain or complex. Statistical reconstruction is more general and is not limited by the pore size. Statistics of the pore space are obtained from readily available experimental data such as thin-section images. Using only single and two-point statistics in the reconstruction often underestimates the pore connectivity, especially for low porosity materials. We use multiple-point statistics for pore space reconstruction that preserves higher-order information, describing the statistical relation between multiple spatial locations. This is a general method that gives images that preserve typical patterns of the void space seen in thin sections. The method is tested on a carbonate sample from the Middle East. Permeability is predicted directly on the 3D images using the lattice Boltzmann method. The numerically estimated results are in good agreement with experimentally measured permeability. Furthermore, this method provides an important input for the creation of geologically realistic networks for pore-scale modeling to predict multiphase flow properties.
10931 Development of automated history-matching program based on Genetic Algorithm for X-ray CT core flooding experiment SCA 2004 International Symposium
2004/10/7
Noriyuki Tokuda, Shunya Takahashi(Japan Oil, Gas and Metals National Corporation), Makoto Watanabe(Japan Oil Development), Takeshi Kurose(CRC Solutions) Research Project Team on Carbonate Reservoir
[Abstract] Recently it has become a common practice to construct 3D coreflooding simulation model to interpret water displacement experiments conducted under X-ray CT scanning. The unknown grid block parameters i.e. kro/krw and Pc curves are required to be optimized to get reasonable matching with experimental data such as changes of grid block water saturation. In order to evaluate the matching process efficiently a new automated history-matching program has been developed. This program applies Genetic Algorithm to optimize several coefficients for normalized kro/krw and Pc curves for each litho-facies. Several blind tests were carried out on hypothetical coreflooding models by changing the conditions of velocity and wettability to investigate the degree of accuracy and limitation of the program. The result of the reproducibility of the relative permeabilities was excellent for both water-wet and oil-wet cases regardless the velocity of coreflooding. On the other hand, the degree of reproducibility was not necessarily satisfactory for capillary pressure curves especially in high velocity case. Sensitivity of the controlling parameter in Genetic Algorithm such as crossover rate and mutation ratio was also investigated. The suitable values are estimated, though no simple trend was found. The program was finally applied to the interpretation of actual water displacement tests on oil-wet carbonate cores. The program successfully gave a reasonable set of kro/krw and Pc curves for each litho-facies and demonstrated its capability of grid block parameter optimization.
10930 Upscaling Method of Relative Permeability from Plug Core to Whole Core SCA 2004 International Symposium
2004/10/7
Shunya Takahashi, Noriyuki Tokuda, Toshiyuki Nakashima(Japan Oil, Gas and Metals National Corporation) Research Project Team on Carbonate Reservoir
[Abstract] This paper presents the results of the interpretation of several unsteady-state coreflood experiments and discusses a method to estimate the relative permeability of the whole core using the data of the smaller scale cores and their characteristics. A water displacement test was conducted on a heterogeneous carbonate whole core (target core), then a series of the same test followed on the several plug cores that were extracted from the target core. Each test on the plug cores was interpreted by 3D coreflood simulation model that was constructed based on the detailed core characterization data. A newly developed simulation matching program called GEMAP *(1) that adopted genetic algorithm was employed to derive a set of normalized kro/krw and Pc curves representing each pore-type as grid data. The relative permeability curves of the plug cores were computed by the two-phase upscaling in-house program called CAVLUP *(2) that was initially developed for reservoir-scale upscaling problem. Both capillary-limit and viscous-limit upscaled kro/krw curves were computed by the program. The kro/krw curves were also determined by different method i.e. steady-state coreflood simulation and compared with the upscaled curves. The result showed that the capillary-limit upscaling method could reasonably reproduce the kro/krw curve generated by steady-state coreflood simulation of the same displacement velocity to that of the actual experiment. Based on the statistical data of porosity, permeability and pore-type, 3D stochastic models were constructed for the target core. A total of 100 kro/krw curves were computed using CAVLUP. On the other hand, 3D deterministic model was constructed to re-optimize the kro/krw and Pc curves of each pore-type and compute kro/krw curve by simulation matching. The result showed that the average upscaled curve of the stochastic models was close to that of the optimized model. It was concluded that the kro/krw curve of the target core could be reasonably estimated from plug-core-scale data by the same upscaling method as applied to reservoir scale problem.
10929 Multiple-Point Statistics to Generate Pore Space Images Geostats 2004
2004/9/27-28
Hiroshi Okabe(Japan Oil, Gas and Metals National Corporation, Imperial College London), Martin J. Blunt (Imperial College London) Petroleum Engineering Research Team
[Abstract] Multiple-point statistics (MPS) on a two-dimensional (2D) thin section image is used to generate a three-dimensional (3D) pore space image with an assumption of isotropy for orthogonal planes. The method gives images that preserve typical patterns of the void space seen in thin section. Using only single and two-point statistics in the reconstruction often underestimates the void connectivity, especially for low porosity materials; however, multiple-point statistics method significantly improves the void connectivity. The method is tested on sandstone and carbonate samples. Permeability is predicted directly on the 3D images using the lattice Boltzmann method (LBM). The numerically estimated results are in good agreement with experimentally measured permeability. Furthermore, the method provides an important input for the creation of geologically realistic networks for pore-scale modeling to predict multiphase flow properties.
10924 Analysis of Oil-Water Flow Tests in Horizontal, Hilly-Terrain, and Vertical Pipes(SPE90096) The SPE Annual Technical Conference and Exhibition
2004/9/26-29
Plat Abduvayt(Waseda University), Ryo Manabe(Inpex Co., Ltd.), Tomoko Watanabe(Japan Oil, Gas and Metals National Corporation), Norio Arihara(Waseda University) Petroleum Engineering Research Team
[Abstract] The flow pattern, pressure drop and water holdup were measured for oil-water flow in horizontal, hilly-terrain (}0.5‹and }3‹) and vertical pipelines at a temperature of about 35} 5 ‹C and a pressure of about 245 kPa using the large-scale multiphase flow-test facility of Japan Oil, Gas and Metals National Corporation (JOGMEC). Test lines of 4.19 inch (106.4 mm) ID and 120 m total length were utilized which included a 40 m horizontal or hilly-terrain and a 10 m vertical test sections sequentially connected. The flow pattern was determined by visual observation with video recordings, and a flow pattern map was made for each condition. New flow patterns were identified for horizontal and hillyterrain flow, such as oil flow in a snake-like shape at top of pipe at high rate of water flow, and water flow at bottom of pipe at high rate of oil flow. New holdup and pressure drop data are presented for each flow condition. The flow rate and inclination angle influences holdup and pressure drop behaviors. In vertical flow, when the oil superficial velocity exceeds a certain value, the pressure drop decreases exponentially as the superficial oil velocity increases. Slippage between the phases was analyzed using the measured water holdup plotted against the input water cut with inlet oil flow rate as parameters. It was found that the slippage changed significant with slightly changes in inclination angle. This paper provides new experimental data of flow pattern, water holdup and pressure drop measured particularly at horizontal, hilly-terrain and vertical conditions with largediameter pipes. These are the indispensable information of developing reliable prediction models for oil-water two-phase and gas-oil-water three-phase flow in pipelines.
10917 Report for International Gas Union on Methane Hydrate International Gas Union
Working Committee 1
2004/9/15-17
Yoshihiro Tsuji(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
10916 The challenge of JOGMEC to develop the new GTL process utilizing CO2 contained in natural gas SPE-ATW "High CO2 Gas Field Development and Production"
2004/9/8
Masaru Ihara(Japan Oil, Gas and Metals National Corporation) Research Project Team on Emerging Gas Technologies
[Abstract] Natural gas with clean characteristics in combustion is expected to be the alternative energy resources to oils in the near future, but the natural gas resources more than 5Tcf, which is only around 2% of the discovered natural gas fields, are mainly developed for LNG market, nevertheless further promotion of its utilization will also be beneficial to environmental preservation. The balance around 98% of the natural gas fields are left undeveloped due to almost stranded natural gas reserves, which is generally small or medium range of natural gas fields inappropriate to LNG supply. JOGMEC has been tackling the research and development of the natural gas conversion technology from the year of 1998 till 2004 in collaboration with five Japanese private companies for JAPEX, CHIYODA, COSMO OIL, NIPPON STEEL and INPEX, in order to aim at establishing the option technology to explore stranded gas reserves.
The JOGMEC-GTL process differs from other conventional GTL processes in two main sections:
1) The synthetic gas (“Syngas”) production applies the steam (H2O)/CO2 reforming rather than Auto-thermal Reforming (“ATR”) or Non-catalytic Partial Oxidation (“POX”) used in other processes (“conventional GTL processes”), and
2) The Fischer-Tropsche (“FT”) synthesis employs the slurry reactor with noble metal or non-noble metal catalysts, as compared to the Co or Fe based catalysts used in the conventional GTL processes.
Thus, JOGMEC -GTL process is expected to prominently get effective in energy efficiency as applied against the natural gas reserves containing relatively high CO2. JOGMEC-GTL process is capable to utilize CO2 contained in the natural gas and does not require any O2 supply. Namely, the characteristics of the process in contrast to those of the existing ones using ATR or POX are (1) no use of the O2 generator, (2) no use of the CO2 removal unit, and (3) no use of the H2 conditioning unit for Syngas. Such facility savings will bring about the remarkable reduction of the plant cost for its election and operation. The suitable conditions for the JOGMEC-GTL process will meet with the plant scale of 5,000 to 15,000 BPSD and the case of CO2 contents being 20 to 40mol% in the natural gas. The economic evaluation does indicate that the JOGMEC-GTL process is more economical than the conventional ones when applied under those conditions.
Our challenges conducted until the end of 2003 have delivered the outcomes (1) recorded around 5,000 operation hours by the identical catalyst of Syngas production and (2) produced GTL products at continuous daily rate 7.3BPSD exceeding the design capacity of 7BPSD at the Yufutsu GTL pilot plant in September 2003, supported by the promising catalysts of syngas production and FT synthesis and the attained efficient total process. Our new challenges also have been commenced focusing on (1) the enhancement of the promising catalysts of Syngas production and FT synthesis through the evaluation of the long run reliability and (2) the development of scale-up methods for the total process.
This presentation introduces the outline and the characteristics of JOGMEC-GTL process, characteristics of GTL products, the catalysts performance of syngas production and FT synthesis viewing the current test results derived from the Yufutsu GTL pilot plant, and the project roadmap viewing the economic evaluation in the feasibility study between JOGMEC and Pertamina.
10915 Interfacial Tension Measurement between Oil and Gas Phase under High Temperature and High Pressure Condition : Effect of Pressure on Interfacial Tension and Comparison of Minimum Miscible Pressure by Vanishing Interfacial Tension Technique and Slim Tube Test Method 25th Annual Workshop & Symposium, Collaborative Project on Enhanced Oil Recovery, IEA
2004/9/6
Komei Okatsu(Japan Oil, Gas and Metals National Corporation) Petroleum Engineering Research Team
[Abstract] One of the most important factors that affect oil displacement efficiency on gas flooding is interfacial tension between oil and injected gas. But the behavior of interfacial tension under high temperature and high pressure has not investigated so much. For the investigation of gas flooding, an interfacial tension measurement apparatus based on pendant drop method, using a high temperature and pressure visual cell and PVT apparatus have been developed. Combining the visual cell for the measurement and PVT apparatus, Interfacial tension can be measured under complete equilibrium condition and density of liquid phase can be measured by the density meter. This paper presents the outline of the apparatus and the results of the interfacial tension measurement between 3 crude (recombined) oil and CO2 systems In each case, the pressure effect on interfacial tensions were investigated and Minimum Miscibility Pressure (MMP) by Vanishing interfacial tension (VIT) technique and Slim Tube Test method were compared with.
10914 Observation of Natural Gas Hydrate Dissociation in Natural Sediments with X-ray CT Scanner 32nd International Geological Congress, in Firenze
2004/8/28
Toshiharu Okui(Japan Oil, Gas and Metals National Corporation), Takashi Uchida(Japan Petroleum Exploration), Yoshihiro Matsuda(Tokyo Univ.) Methane Hydrate Research Project Team
[Abstract] Dissociation of gas hydrate in natural core samples was visualized with an X-ray CT scanner. The natural core samples were obtained at the JAPEX/JNOC/GSC et al. Mallik 5L-38 Production Well in Canada. During the measurement confining and pore pressure were independently controlled and temperature of the sample was carefully maintained. Both depressurizing and heating processes, which are considered as typical potential gas production processes from hydrates, were simulated in laboratory scale for the field gas production tests. As a result, dissociation was clearly observed as difference of CT values. Obtained three-dimensional CT data in the cores were processed to image dissociation behavior. It was indicated that dissociation behavior was strongly influenced by quality of samples, especially saturation and distribution of hydrates in sediments. Natural core samples, transported from Canada to Japan, were set in a core holder especially designed for this experiment. Conditions were carefully changed into hydrate dissociation zone. Difference of dissociating behavior in depressurizing and heating processes was observed respectively with X-ray CT scanning. Dissociation was clearly distinguished as CT value change that was mainly caused by gas phase formation. Dissociation behavior depended upon occurrence of gas hydrate. Commonly gas hydrate in all samples immediately began to dissociate when they were exposed to theoretical dissociation conditions of pure methane hydrate both in depressurizing and heating processes. However, highly saturated sample dissociated very slow. Additionally after the pressure was sufficiently released the gas expanded through pore space. It was suggested that the gas could not move in pore space so smoothly after dissociation.
10911 Hydrogen isotope fractionation by microbial methanogenesis in culture experiments 32nd International Geological Congress, in Firenze
2004/8/27
Hideyoshi Yoshioka, Susumu Sakata, Yoichi Kamagata(National Institute of Advanced Industrial Science and Technology, AIST ) Methane Hydrate Research Project Team
[Abstract] Occurrence of microbial methane has been reported in anoxic sediments of a wide variety of environments, including freshwater, marine environments, and deep biosphere. The methane has variations in stable carbon and hydrogen isotopic compositions. It has been proposed that two primary pathways of methanogenesis, CO2 reduction and acetate fermentation, can be distinguished by comparing the carbon and hydrogen isotopic compositions of the methane with those of the coexisting carbon dioxide and formation water. In this study, we present hydrogen and carbon isotopic compositions of methane produced by a thermophilic hydrogen-utilizing methanogen, Methanobacterium thermoautotrophicus. Cultures were grown at 55 and 65 degrees under an atmosphere initially pressurized at 2 atm with H2 and CO2 in proportion 80: 20. For isotope analyses of methane at different stages of growth, the cultures in three serum bottles were grown at each temperature for 24, 47, and 72 hours, respectively, followed by the collection of gases from the headspace. We found that hydrogen isotope fractionation factor ranged from 0.69 to 0.72, showing a decreasing trend with the progress of the growth phase. These values are similar to that calculated from data reported for culture experiments of Methanobacterium formicium and that reported from incubation experiments of a paddy soil . However, in the cross-plot of hydrogen isotope ratios of methane and ambient water, our data points were plotted far from the regression lines for isotope data of marine sediments and natural gas deposits. We consider that the inconsistency between our culture experiments and field measurements would be caused by some culture conditions which rarely occur in natural environments. The high concentration of hydrogen gas and the high temperature of growth are among the candidates.
10910 Population Analysis of Methanogenic Archaea in Subterranean Gas Fields 10th International Society for Microbial Ecology
2004/8/22-27
Toshihiro Hoaki(Taisei Corporation) Methane Hydrate Research Project Team
[Abstract] Natural gas deposit of dissolved in water type is distributed into not only onshore site but also offshore site. Some fields are thought to be formed by microbial effect, however the origin of gas and its formation mechanism is not well known. Anaerobic microbial consortia including methanogenic archaea produce CH4 from organic matter and the CH4 producing process is observed in various places. In this study, we focused on onshore subterranean gas fields at Mobara and Niigata, which are thought to be microbial origin. Sludge is precipitated within the formation water in production well. Therefore we collected the sludge from the well. Salinity of formation water was similar to that of seawater. Viable cell density of methanogen was estimated to approx. 105 cells/g-sediment, while total cell density was approx. 107 cells/g-sediment in both Mobara and Niigata. 16S rDNA clone analysis revealed that a variety of methanogen was detected including the uncultured clone cluster. Therefore CH4 could be produced in subterranean field even now. In addition, a similar to Thermoplasma clone and other unknown archaeal clone was also detected in the sludge from a deeper field, which is produced from 1,000m depth. This result indicates that microbial consortia could be depending on a temperature and thermophilic or hyperthermophilic methane producing consortia may be existed in more deep underground.
10912 Wide-angle Seismic Study of Gas Hydrate Accumulations in the Eastern Nankai Trough, off Tokai, Japan 32nd International Geological Congress, in Firenze
2004/8/20-28
Maarten Vanneste, Stephanie Guidard, Jurgen Mienert(University of Tromso), Eiichi Asakawa, Peter Ward(JGI, Inc.) Methane Hydrate Research Project Team
[Abstract] We used wide-angle multi-component ocean bottom seismometer (OBS) data in combination with conventional multi-channel and high-resolution 3D seismic data to study the distribution and characteristics of gas hydrates and free gas accumulations in the sediments of the eastern Nankai Trough, a prominent accretionary wedge, off Tokai, Japan. Seismic data reveal a very complex and dynamic sedimentation history, dominated by dipping turbidite and contourite deposits, active channels, folds, high-angle faults, fluid migration, cold seeps and mass wasting events. Despite this, the bottom-simulating reflection (BSR), indicative for the presence of gas hydrates and free gas, is easily recognized as a laterally-variable amplitude reflection. The BSR runs sub-parallel to the seafloor morphology, thereby cross-cutting the stratigraphy. Remarkably, the BSR is followed by a faint, oblique and irregular reflection, interpreted as the base of the free gas zone, as evidenced on the 3D data and time slices. While the complex subsurface geology is challenging for wide-angle modelling and inversion procedures, the OBS data allowed us to construct a 9 layer geophysical model for the uppermost 700 m of sediments in the eastern Nankai Trough, in water depths of 930 to 1160 m. Travel-time inversion gives elevated P-wave velocities, reaching values of up 2100 m/s. Such high P-wave velocities can be explained by a partial hydrate saturation of pore space of up to 20% within the ~200 m thick hydrate accumulation zone. The BSR at ~320 mbsf coincides with a significant drop in P-wave velocity to values between 1580 and 1750 m/s, suggesting the presence of small pockets of free gas. This lower-velocity layer is ~80 m thick. The S-wave velocities were subsequently derived by event correlation, time picking and forward modelling of the wide-angle data, and are up to 700-750 m/s in the hydrate zone. In the gassy layer underneath the BSR, we observe a small decrease of S-wave velocity. This might indicate a weak hydrate cementation of the sedimentary matrix. In the deeper section however, the surprisingly high P- and S-wave velocities point towards over-consolidated sediments, attributed to the particular compressional tectonic setting. The velocities show good correspondence with well-logging data from nearby boreholes. The geothermal gradient, inferred from the BSR, equals 40‹C/km.
10909 Methane Hydrate Detection Using Dense Velocity Analysis, Offshore Tokai 3D, Japan 2004 Western Pacific Geophysics Meeting
2004/8/17
Takashi Hamajima, Masami Hato(JGI, Inc.), Takao Inamori(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] In order to detect high velocity anomaly zones suggesting the existence of methane hydrate, velocity analysis of reflection seismic data was conducted. For a delineation of detailed velocity structure, dense velocity analysis was performed using an automatic velocity picking tool we have developed. Significant reduction in analysis time enables the application to large 3D seismic data. Offshore Tokai 3D seismic data, acquired over the Nankai Trough, Japan, was analyzed at a 50m interval in both in-line and cross-line directions. The analysis covered an area of 400 square kilometers with a total of 159750 CMPs. Results of this analysis clearly show high velocity anomaly above the BSR, and velocity reversal at the BSR. Viewing the interval velocity volume with the horizon slices parallel to the sea floor facilitates recognition of the extent of the velocity anomaly. The difference between estimated interval velocities and a standard velocity trend such as the Hamilton's equation provides another viewpoint to highlight the velocity anomaly zones. Further studies will include the calibration of velocities with well log data for a reliable estimation of hydrate bearing zones.
10908 Delineation of gas hydrate-bearing sediments by multi seismic attributes using three-dimension seismic survey, offshore Tokai, Japan. 2004 Western Pacific Geophysics Meeting
2004/8/17
Takao Inamori(Japan Oil, Gas and Metals National Corporation), Masami Hato(JGI, Inc.) Methane Hydrate Research Project Team
[Abstract] METI, Ministry of Economy, Trade and Industry of JAPAN, started "Japan's Methane Hydrate Exploitaion Program" since the fall of 2001. Bottom Simulating Reflectors (BSRs) were widely found on the marine seismic survey data acquired offshore Japan, especially in the shelf slope near the Nankai Trough. METI conducted three-dimension seismic survey in 2002. BSRs indicate the existence of gas hydrate, they, however, do not estimate the amount of gas hydrate as the reservoir parameters. In order to estimate the amount of gas hydrate accurately, we have to get the more detailed reservoir parameters such as the gas hydrate saturation, the porosity or th shickness of the gas hydrate reservoir layer. We took notice of the relationship between the gas hydrate and P-wave interval velocity from the NMO velocity analysis and P-wave impedance, S-wave impedance or pseudo Poisson's ratio from the multi attibutes analysis using the three-dimension seismic survey data. We delineated the gas hydrate-bearing sediments offshore Tokai Japan. We compared multi attributes data and borehole logging data.
10907 Velocity structure of the Kumano Basin in the Nankai Trough 2004 Western Pacific Geophysics Meeting
2004/8/15-20
Tatsuo Saeki, Jun Matsushima(Japan Oil, Gas and Metals National Corporation), Sumito Morita(National Institute of Advanced Industrial Science and Technology, AIST), Masao Hayashi(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] Conventionally, BSR (bottom simulating reflector), which is considered to be a bottom of the methane hydrate bearing sediment, has been used for delineation of horizontal distributions of methane hydrate layers and their base structures. Detailed velocity analysis is also expected to provide additional knowledge including vertical distributions or some others attributes, because the P-wave velocity of methane hydrates is higher than them of surrounding sediments. The velocity structure of the Kumano basin in the Nankai trough using 2D seismic data was analyzed in order to evaluate the methane hydrate potential. Because of complex geological structure in the survey area and large feathering angle occurrence in the data acquisition, velocity scan panels with the conventional stacking method had a considerable amount of artificial high and low velocity anomalies. Against the above problem, the pseudo-3D diffraction stacking method with multi 2D lines data was applied successfully for the velocity analysis. At the meeting, we will show details of the velocity analysis process and the obtained velocity structure.
10913 Organic Geochemistry of Marine and Terrestrial Gas Hydrate Deposits 2004 Gordon Research Conference on Organic Geochemistry
2004/8/9-12
Amane Waseda, Takashi Uchida(Japan Petroleum Exploration Co., Ltd.), Masaru Nakamizu(Japan Oil, Gas and Metals National Corporation) Methane Hydrate Research Project Team
[Abstract] Gas origin and migration in marine gas hydrate-bearing sediments in the Nankai Trough, Blake Ridge and Cascadia margin, and terrestrial gas hydrate-bearing sediments in the Mackenzie Delta are investigated using gas molecular and isotopic data. In the Nankai Trough and Blake Ridge, the carbon and hydrogen isotope compositions of methane show that the methane in gas hydrates is generated by microbial reduction of CO2. In the Cascadia margin, the origin of methane is interpreted to be mainly microbial with a trace of thermogenic methane. In the Mackenzie Delta, the isotopic data show that the gas in gas hydrate is generated by thermogenic decomposition of kerogen. Gas isotope profiles in the Nankai Trough and Blake Ridge suggest progressive decrease in microbial activity with depth and upward gas migration through the sediment column. Based on the geochemical and geological data, gas migration process is inferred to be slow pervasive flow in the Blake Ridge, active flow to permeable sand layer in the Nankai Trough, very active flow to surface through fault in the Cascadia margin, and long migration through fault in the Mackenzie Delta.
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