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Abstract
10894 The Challenge of Japan Oil, Gas and Metals National Corporation [JOGMEC] to develop the new GTL process,- GTL process utilizing CO2 contained in the natural gas to explore stranded gas reserves TOG 2004, Forum and Exihition,28-30 June 2004, Tripoli, Libya
2004/6/28-29
Kazuhito Katakura(Japan Oil, Gas and Metals National Corporation) Research Project Team on Emerging Gas Technologies
[Abstract] JOGMEC has been tackling the research and development of the natural gas conversion technology, Gas to Liquid ("GTL") since the fiscal year 1998 in collaboration with five Japanese private companies for JAPEX, CHIYODA, COSMO OIL, NIPPON STEEL and INPEX for the purpose of establishing the option technology to explore stranded gas reserves.The JNOC-GTL process differs from other conventional GTL processes in two main sections:
1) The synthetic gas (“Syngas”) production applies the steam (H2O)/CO2 reforming and
2) The Fischer-Tropsche (“FT”) synthesis employs the slurry reactor with noble metal or non-noble metal catalysts.
JNOC-GTL process is capable to utilize CO2 contained in the natural gas and it never require (1) O2 generator, (2) CO2 removal unit, and (3) H2 conditioning unit for Syngas. Such facility savings will bring about the remarkable plant cost reduction for its election and operation. The economic evaluation does indicate that the JNOC-GTL process is particularly much more economical than the conventional ones when applied under the condition of being 20 to 40mol% CO2 contents in the natural gas.
Our challenges at the end of 2003 have delivered the outcomes (1) recorded around 5,000 operation hours of Syngas production and (2) produced GTL products at daily rate 7.3BPSD in higher productivity at the Yufutsu GTL pilot plant. Our new challenges also have been commenced focusing on (1) the enhancement of the promising catalysts of Syngas production and FT synthesis through the evaluation of the long run reliability and (2) the development of scale-up methods applying the computational fluid dynamics to the total process.
This paper introduces the outline and the characteristics of JNOC-GTL process, characteristics of GTL products, the catalysts performance of Syngas production and FT synthesis, process development with scale-up methods, and the project roadmap viewing the economic evaluation in the feasibility study between JOGMEC and Pertamina.
10879 Lubricity of liquefied gas assessment of multi-pressure/temperature high-frequency reciprocating rig (MPT-HFRR) -DME Fuel for Diesel- SAE Fuels & Lubricants Meeting
2004/6/8-10
Kouseki Sugiyama(Iwatani International Corporation), Masataka Kajiwara(Japan Automobile Research Institute), Masahiro Fukumoto(NOF Corporation), Makihiko Mori, Shinichi Goto(National Institute of Advanced Industrial Science and Technology, AIST), Tomoko Watanabe(Japan Oil, Gas and Metals National Corporation) Research Project Team on Emerging Gas Technologies
[Abstract] In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) which can be used also for liquefied gas fuel tests was manufactured based on a Diesel fuel lubricity test apparatus, but having a construction which can be used also for conventional test methods. In this apparatus, when lubricity tests were performed using a calibration standard sample and atmospheric pressure or high pressure, essentially constant values were obtained, so it was determined that it could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. As a result, it was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400_m or less, and a value close to the measurement result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.
10878 Geometry of the fracture for cuttings reinjection operation and solid concentration: A numerical study GulfRock 2004 (6th North American Rock Mechanics Symposium)
2004/6/8
Koji Yamamoto(Japan Oil, Gas and Metals National Corporation) Petroleum Engineering Research Team
[Abstract] In order to evaluate the growth of fractures for cuttings re-injection, a solid transport model is included in a solidfluid coupled hydraulic fracturing simulator. The fracture geometry is a critical factor affecting the safety of the re-injection operation, and solid particle flow in the fractures is known to have a dominant effect on the fracture propagation. To improve the accuracy of the simulation, the finite element method (FEM) is introduced for modeling the particle motion in the fracture fluid. In the model, opening of the fracture, interaction between multiple particles, and change in viscosity by the solid concentration are taken into account. Numerical examples shown here reveal that the fracture geometry is highly dependent on the concentration of the solid due to the change of gravity and slurry viscosity. The injected solid concentration is one of the few controllable parameters, thus the results suggest the feasibility of geometry control.
10881 Development of Synthesis Gas Production Catalyst and Process 7th Natural Gas Conversion
2004/6/7
Fuyuki Yagi, Shuhei Wakamatsu, Ryuichirou Kajiyama, Mitsunori Shimura(Chiyoda Corporation), Yoshifumi Suehiro(Japan Oil, Gas and Metals National Corporation) Research Project Team on Emerging Gas Technologies
[Abstract] The CO2 reforming catalyst and process have been developed. The commercial size CO2 reforming catalyst has been demonstrated its activity and stability in the GTL pilot plant tests for more than 1,100 hours, and the first GTL oil from natural gas in Japan was produced in November 2002. In these tests, synthesis gas was generated by CO2 and H2O reforming with low CO2/Carbon and H2O/Carbon ratios in feed gas composition. The proprietary catalyst which has high resistance against carbon deposition could allow the stable operation under CO2 and H2O reforming conditions. The CO2 reforming simulator could well represent the results of the pilot plant tests. The proposed process showed superior economics on the feasibility studies of applications to GTL processes.
10871 The Challenge of Japan Oil, Gas and Metals National Corporation [JOGMEC] to develop the new GTL process, -GTL process utilizing CO2 contained in the natural gas to explore stranded gas reserves- The CWC Group of Companies
2004/5/18
Katakura Kazuhito(Japan Oil, Gas and Metals National Corporation) Research Project Team on Emerging Gas Technologies
[Abstract] JOGMEC has been tackling the research and development of the natural gas conversion technology, Gas to Liquid ("GTL") since the fiscal year 1998 in collaboration with five Japanese private companies for JAPEX, CHIYODA, COSMO OIL, NIPPON STEEL and INPEX for the purpose of establishing the option technology to explore stranded gas reserves.The JNOC-GTL process differs from other conventional GTL processes in two main sections:
1) The synthetic gas (“Syngas”) production applies the steam (H2O)/CO2 reforming and
2) The Fischer-Tropsche (“FT”) synthesis employs the slurry reactor with noble metal or non-noble metal catalysts.
JNOC-GTL process is capable to utilize CO2 contained in the natural gas and it never require (1) O2 generator, (2) CO2 removal unit, and (3) H2 conditioning unit for Syngas. Such facility savings will bring about the remarkable plant cost reduction for its election and operation. The economic evaluation does indicate that the JNOC-GTL process is particularly much more economical than the conventional ones when applied under the condition of being 20 to 40mol% CO2 contents in the natural gas.
Our challenges at the end of 2003 have delivered the outcomes (1) recorded around 5,000 operation hours of Syngas production and (2) produced GTL products at daily rate 7.3BPSD in higher productivity at the Yufutsu GTL pilot plant. Our new challenges also have been commenced focusing on (1) the enhancement of the promising catalysts of Syngas production and FT synthesis through the evaluation of the long run reliability and (2) the development of scale-up methods applying the computational fluid dynamics to the total process.
This paper introduces the outline and the characteristics of JNOC-GTL process, characteristics of GTL products, the catalysts performance of Syngas production and FT synthesis, process development with scale-up methods, and the project roadmap viewing the economic evaluation in the feasibility study between JOGMEC and Pertamina.
10692 Fault Characterization by Seismic Attributes and Geomechanics in a Middle East Oil Field Geo Arabia Vol.9 No.2
2004/4/1
Yoshihiko Tamura, Keiichi Furuya(Japan Oil Development Co., Ltd.), Futoshi Tuneyama(Stanford University), Hitoshi Okamura(Japan National Oil Corporation) Research Project Team on Carbonate Reservoir
[Abstract] Faults and fractures were interpreted using attributes that were extracted from a 3-Dseismic data set recorded over a Lower Cretaceous Thamama oil field in offshore Abu Dhabi, United Arab Emirates. The Thamama reservoir has good matrix porosity (frequently exceeding 20%), but poor permeability (averaging 15 mD). Because of the low permeability, faults and fractures play an important role in fluid movement in the reservoir. The combination of the similarity and dip attributes gave clear images of small-displacement fault geometry, and the orientation of subseismic faults and fractures. The study better defined faults and fractures and improved geomechanical interpretations, thus reducing the uncertainty in the preferred fluid-flow direction. Two fault systems were recognized: (1) the main NW-trending fault system with mapped fault-length often exceeding 5 km; and (2) a secondary NNE-trending system with shorter faults. The secondary system is parallel to the long axis of the elliptical domal structure of the field. Some of the main faults appear to be composed of en-echelon segments with displacement transfer between the overlapping normal faults (relay faults with relay ramps). The fault systems recognized from the seismic attributes were correlated with well data and core observations. About 13 percent of the fractures seen in cores are non-mineralized. The development of the fault systems was studied by means of clay modeling, computer simulation, and a regional tectonics review. The existing fluid-flow characteristics of individual faults and fractures in the field can be modeled using the present-day stress regime, with the maximum horizontal stress oriented north-northeast. Slip-tendency and dilation-tendency analyses simulating present-day regional stress conditions are indicators of fault and fracture transmissibility. The NNE-striking secondary fault system is parallel to the present day maximum horizontal stress and could act as a flow conduit in the reservoir.
10860-2 Overview of the MITI Nankai Trough Wells: A Milestone in the Ealuation of Methane Hydrate Resources Resource Geology Vol.54, No.1
2004/3/30
Yoshihiro Tsuji, Hisashi Ishida, Masaru Nakamizu(Japan Oil, Gas and Metals National Corporation), Ryo Matsumoto(The University of Tokyo), Satoshi Shimizu(Ministry of Economy, Trade and Industry) Methane Hydrate Research Project Team
[Abstract] As a hydrocarbon consuming country, Japan has been interested in methane hydrate as one of possible future energy resources, as BSRs which is regarded to suggest the existence of hydrate are widely distributed offshore Japan. A well for hydrate research and for exploration of Tertiary conventional structure, named MITI”Nankai Trough'' was drilled in late 1999 to early 2000, in the Northwest Pacific Ocean off Central Japan at a location of which water depth is 945m. Six wells, which are two pilot wells, the main hole and three post survey wells, were drilled in the area of BSR distribution. Distances among each hole are 10m to 100m. The wells excluding the first well which was drilled for examining free gas bubbling confirmed the occurrence of hydrate by LWD, wireline logging, and/or coring by PTCS and conventional method. Based on the results of Resistivity, Sonic, FMI, CMR, and other logging data effective for methane hydrate evaluation, four methane hydrate bearing sand rich intervals of turbidite fan deposits were recognized. Methane hydrate fills pore spaces among grains and the saturation was 80% in the layers in a maximum. The thickness of each turbidite sand layer is less than a meter and the total thickness of the four sandy beds with methane hydrate is 12 to 14m. The bottom depth of high hydrate concentration was correlated with the depth of BSR by VSP. Having the result of the well, Japan has started a methane hydrate exploitation program.
10860 Using 2D and 3D Basin Modelling to Investigate Controls on Hydrocarbon Migration and Accumulation in the Vulcan Sub-basin, Timor Sea, North-Western Australia APPEA 2004 (Australian Petroleum Production & Exploration Association) (APPEA Journal 2004)
2004/3/30
Tetsuya Fujii (Japan Oil, Gas and Metals National Corporation) Geology & Geophysics Research Team
[Abstract] 2D and 3D basin models have been constructed of the southern and central parts of the Vulcan Sub-basin region, in the Timor Sea. This work was carried out in order to better elucidate the petroleum migration and accumulation histories, and exploration potential, of the region.
2D/3D modelling in the Swan Graben indicates that horizontal and downward oil expulsion from the source rocks of the Late Jurassic Lower Vulcan Formation into the Plover Formation sandstone was active from the Early Cretaceous to the present day. Oil migration from the Lower Vulcan Formation into the Late Cretaceous Puffin Formation sands in the Puffin field was simulated by lateral migration along the bottom of an Upper Vulcan Formation seal and by vertical migration above the seal edge. Modelling also indicates that Late Jurassic sequences over the Montara Terrace are thermally immature, and did not contribute to the hydrocarbon accumulations in the region. On the other hand, 3D modelling results indicate that Middle Jurassic Plover Formation in the Montara Terrace became thermally mature after the Pliocene and hence it could contribute both to the hydrocarbon accumulations and the overall hydrocarbon inventory in the area.
In the southern Cartier Trough, the Lower Vulcan Formation is typically at a lower thermal maturity than that seen in the Swan Graben, due to a combination of a relatively recent (Pliocene) enhanced burial history and a thinner Lower Vulcan Formation. Here, horizontal and downward oil/gas expulsion from the Lower Vulcan Formation into the Plover Formation sandstone was active from the Late Tertiary to present day, which is significantly later than the expulsion in the Swan Graben. Oil migration from the Lower Vulcan Formation into the Jabiru structure via the Plover Formation carrier bed, was simulated in both 2D and 3D modelling. In particular, 3D modelling simulated oil migration into the Jabiru structure, not only from the southern Cartier Trough after the Miocene, but also early migration from the northern Swan Graben in the Early Cretaceous.
In the central Cartier Trough, the areal extent of both generation and expulsion increased as a result of rapid subsidence from about 5 Ma to present day. This Pliocene loading has resulted in the rapid maturation of the Early to Middle and Late Jurassic source system, and expulsion of oil very recently.
10859 New Analytical Correction for Multi-Phase Flow Effect in Near-Well Regions of Coarse Grid System SPE Asia Pacific Conference on Integrated Modeling for Asset Management
2004/3/29
Toshinori Nakashima, Masahiko Nomura(Teikoku Oil Co. Ltd.) Research Project Team on Carbonate Reservoir
[Abstract] Recently, the geostatistical approach has been very common for the pixel-base reservoir modeling, therefore the reservoir engineers are often requested to generate the flow simulation model by up-scaling such pixel-base reservoir model with a huge number of cells. In the up-scaling process, not only the production and injection performances at each well but also the fluid properties in the near-well region in the coarse-grid reservoir model have to reasonably agree with those in the fine-grid reservoir model. However, it is known that the injection pressure at the well is computed sometimes incorrectly in the coarse-grid reservoir model. This is because total mobility at the injection well is defined by the finite difference based average saturation in the injection well grid block, in other words the saturation gradient that would appear in the near-well region is ignored in such coarse-grid system.
A new analytical technique is proposed to eliminate such coarse-grid effects. This technique gives effective total mobility accounting for the saturation and pressure distribution in the near-well region by a following procedure.
The areal average saturation in the injection well grid block is calculated analytically by the extended radial displacement problem newly derived from the Buckley-Leverett linear displacement problem, taking account of pressure difference between the injection well and the injection well grid block. Consequently, the corrected total mobility is provided, by defining new value of total well index and transmissibility.
The results computed by this new technique are reasonably agreed with the analytical solution of radial problem.
The developed technique would contribute to 1) the fast computation of the effective multiphase flow properties in the near-well region, 2) the improvement of accuracy in the calculation of injection pressure in the coarse-grid system, and 3) the up-scaling approach to eliminate coarse-grid effects.
10857 Stacking Velocity Analysis at the Local Point Utilizing Diffraction Stacking Method The 8th International Symposium on Recent Advances in Exploration Geophysics in Kyoto (RAEG2004)
2004/3/10
Tatsuo Saeki, Jun Matsushima (Japan Oil, Gas and Metals National Corporation), Sumito Morita(National Institute of Advanced Industrial Science and Technology), Masao Hayashi (Japan Oil, Gas and Metals National Corporation) Geology & Geophysics Research Team
[Abstract] In the conventional stacking velocity analysis of 2D reflection seismic data processing, the complex subsurface structure and the irregular acquisition geometry frequently produce artificial velocity anomalies. In order to investigate the true velocity structure in the 2D survey area of the Kumano Basin in Nankai Trough, pseudo-3D diffraction stacking method with multi 2D lines data was applied for the stacking velocity analysis. This method enabled to cancel artificial velocity anomalies and provide the analysis accuracy similar to the 3D pre-stack time migration.
10854 Methane Hydrate Detection Using Dense Velocity Analysis 2003 Fall meeting of American Geophysical Union
2003/12/10
Takashi Hamajima (JGI Inc.), Takao Inamori, Masami Hato (Japan Petroleum Exploration Co., Ltd.), Eiichi Asakawa (JGI Inc.), Nobutaka Oikawa (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] As one of approach to evaluating the total amount of methane hydrate, a method utilizing the results of velocity analysis on reflection seismic exploration data is studied. Well log sonic data reveals that the velocity of the methane hydrate bearing zone is greater than that of surrounding sediments. Thus, the velocity information can be used for detection of the methane hydrate zone.\\In order to delineate detailed velocity variations, a dense velocity analysis is performed using an automatic velocity picking tool. Because the target depth of this analysis is fairly shallow ( less than 400m below sea bottom ), a simple algorithm can be used for the picking.\\Dense velocity analysis is applied to 2D marine seismic data acquired over the Nankai Trough, Offshore Japan. Comparison between automatic and manual picking results showed a similar trend at the shallower zone above BSR. The processing time, however, is considerably different; it takes several days for manual picking against a few minutes for automatic picking.\\In the automatic picking process, the velocity trend is also estimated. The difference between actual velocity and velocity trend provides another viewpoint for the delineation of velocity anomaly zone.\\On going work includes an analysis of 3D marine seismic data in the Nankai Trough. Provisional results will be shown in this meeting.
10853 High Resolution, Deep-Tow Seismic Survey to Investigate Methane Hydrate-Bearing Sediments, Nankai Trough, Offshore Japan 2003 Fall meeting of American Geophysical Union
2003/12/10
Peter Ward, Eiichi Asakawa (JGI Inc.), Shoshirou Shimizu (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] A 2D deep-towed seismic survey was carried out over part of the Nankai Trough, Offshore Japan, in 1996. The area is known to have a major accumulation of methane hydrate; conventional seismic surveys have mapped thousands of sq. km. of BSR events, and the presence of methane hydrate was confirmed by a MITI research well in 2000. The objective of the deep-towed survey was to obtain high resolution stack and velocity profiles of the methane hydrate-bearing sediments down to the BSR, which occurs at around 300 msec below the sea bottom in this area. The data was acquired using the "Deep-Towed Acoustics/Geophysics System (DTAGS), developed by the Naval Research Laboratory, USA. Both the source and the hydrophone cable are towed close to the seabed, allowing a "close look" at the shallow sediments. The source is a vibrator-type Helmholtz transducer with a 0.25 sec sweep from 250-650 Hz. The hydrophone cable has 48 channels and a maximum offset of 620m. This paper focuses on the data processing, carried out in 1998 and 2002. The main challenge in the processing was to handle the floating acquisition datum with source and receiver depths being maintained at typically 200-300 m above a varying seabed. The measured depths had to be corrected by residual statics derived from picks of the sea bottom reflection event. A total of around 200 km of data was processed, with water depths of 700-1400 m. The results showed that it is possible to obtain high resolution profiles and velocity data, and that it is also possible to fail to achieve such data. Success largely depends upon control of the depths during acquisition; they should be kept smoothly varying and measured as accurately as possible. The deep-tow system has the advantage over conventional data in water depths of around 1000 m or deeper, for zones close (within 100's m) to the seabed. The advantage of the system becomes greater with increasing water depth.
10845 A Trial of delineation of Methane Hydrate-bearing Zone using Seismic Attribute - for quantification of methane hydrate volume- First International Workshop on Continental Margin Tectonics and Gas Hydrates
2003/11/16
Masami Hato, Takao Inamori (Japan Petroleum Exploration Co., Ltd.), Jun Matsushima (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] Following the confirmation of methane hydrate (hereafter called just as "hydrate") occurrence in Nankai Trough offshore Japan by drilling in 1999, the national project named "MH21" started. The most important and hurried issue to be done is to evaluate the total amount of the hydrate after establishing the geophysical evaluation technique.
Due to the style of the hydrate accumulation, we can easily find the bottom of hydrate-bearing zone by BSR. On the other hand, the top of the hydrate-bearing zone is hard to recognize because of its sparse distribution. Hato & Inamori (2002) introduced the validity of the interval velocity to delineate spatial distribution of hydrate based on the high impedance property of the hydrate.
In order to try more precise delineation of hydrate-bearing zone, we adopt a seismic attribute. Attribute analysis is categorized into 2 class, which is post-stack attribute and pre-stack attribute analysis. In this presentation, we show the result of post-stack hybrid (impedance and attenuation) attribute analysis to the seismic data acquired in Nankai Trough, based on the fact of high impedance of hydrate-bearing zone and hypothesis of low elastic-wave attenuation in the hydrate. This hybrid attribute well indicates the hydrate-bearing interval except some hydrate-bearing layers. We also tried to apply a pre-stack hybrid (impedance and pseudo Poisson's ratio) attribute analysis to the same data based on the purely theoretical approach. The result shows us good coincidence to the result from the post-stack attribute analysis and the well log analysis.
10844 JNOC's GTL Process Development The ‚Sh Vietnam-Japan Dialogue on Energy Cooperation
2003/11/11
Akira Suzuki Research Project Team for Emerging Gas Technologies
[Abstract] 1. GTL Projects Overview
(1) What's GTL and Why?
(2) What's going now?
2.JNOC's GTL R & D Program
(1) Target and Specification
(2) Time Schedule
(3) Organization
(4) Results up to now
3. Conclusion
10842 Development of gas hydrate production systems for gas transportation 3rd International workshop on methane hydrates R&D
2003/11/18-21
Toshiharu Okui, Katsuhiko Bando, Masaru Ihara (Japan National Oil Corporation) Research Project Team for Emerging Gas Technologies
[Abstract] Since Japan has very small amount of domestic natural gas and oil resources, it is important to have options to import energy resources. Natural Gas Hydrates (NGH) has drawn much attention as one of the future gas transportation methods these days. NGH contains 170 times as much gas as its volume under milder conditions, such as at much higher temperature than LNG and lower temperature than pressure cylinders. Therefore, a capital cost of NGH process is estimated lower than that of LNG. There are many reports of laboratory data about basic properties of gas hydrates and some reports about the cost estimation of NGH chain for gas transportation but almost no engineering data for industrial applications.
Japan National Oil Corporation (JNOC) has started research programs to evaluate industrial efficiency of NGH as a gas transportation medium in 1999 with Japanese private companies. First a special attention was paid to collect engineering data of fast and continuous production of hydrates. We are comparing and evaluating typical formation processes, such as spraying, stirring and bubbling, from industrial point of view. Production rate has been optimized. For example, relationship between production rate and condition of pressure and temperature was investigated, and contacting surface area was maximized by controlling droplet size or bubble size. During the study, there have been engineering difficulties to form large amount of hydrate with enough density of gas with bench scale facilities but some of them were successfully overcome by unique original technology of each partner. Results of basic properties investigations by partners are also helpful to solve such problems.
Now the program is fully equipped by not only the production but also shipping and gasification, finally. With those detailed engineering data from all components, more accurate cost of hydrate transportation system will be estimated.
10839 Experimental observation of natural gas hydrate dissociation in sediments 3rd International workshop on methane hydrates R&D
2003/11/18-21
Toshiharu Okui (Japan National Oil Corporation), Takashi Uchida (Japan Petroleum Exploration Co., Ltd.), Yoshihiro Masuda (University of Tokyo) Research Project Team, Methane Hydrate
[Abstract] In order to observe hydrate dissociation in sediment under controlled pressure and temperature, it was suggested that X-ray CT scanner would be a useful. Natural core samples of gas hydrate in sediments were obtained from under permafrost in Canada. Gas hydrates are generally stable at low temperature and high pressure; therefore, conditions should be kept in a tightly packed core holder to observe dissociation phenomenon. In this experiment, confining pressure, pore pressure and temperature were independently controlled during observation. Both depressurizing and heating processes, which are proposed as candidates for gas production processes from natural gas hydrate, were simulated in laboratory.
Natural core samples were set in a core holder especially designed for this experiment. Conditions were carefully changed into hydrate dissociation zone. Difference of dissociating behavior in depressurizing and heating processes were observed respectively with X-ray CT scanning. Obtained CT value data were processed to indicate three-dimensional image of hydrate in sediments. As results, dissociation of the hydrates was clearly observed as difference of CT values. It was suggested that CT value change was mainly caused by gas phase formation.
Dissociation behavior was strongly influenced by quality of samples, especially amount and distribution of hydrates. On the other hand, a common trend was observed. All hydrates immediately began to dissociate when they were exposed to theoretical dissociation conditions of pure methane hydrate. Additionally after the pressure was sufficiently released the gas expanded through pore space.
It was suggested that X-ray CT scanning would be an appropriate technique for observation of natural gas hydrate dissociation in sediments. Detailed studies would be useful to optimize dissociation processes and conditions for gas production from natural gas hydrates.
10838 Challenge for the Development of Full Petroleum System Model -Integration of Three-dimensional Petroleum Migration Model, Geomechanical Model and Source Rock Depositional Model- Geological Society of America 2003 Seattle Annual Meeting
2003/11/5
Akihiko Okui, Kunihiro Tsuchida (Japan National Oil Corporation), Ryosuke Aoyagi, Osamu Kitamura, Kiyoshi Matsubara (Fuji Research Institute Co., Ltd.) Research Project Team, Methane Hydrate
[Abstract] Basin modeling technique was started in 70fs as zero-dimensional source rock maturity model, has evolved to one-dimensional model introducing compaction, heat transfer and kinetic model, and to two-dimensional model with multi-phase fluid flow. Even three-dimensional petroleum migration model has been developed in late 90fs and started using in actual exploration and production projects of oil industry. However, present three-dimensional petroleum migration model is not perfect and lacking enough capability to model essential phenomena in petroleum system such as petroleum migration through faults and fractures, and source rock development. Our solution is to develop additional computer models to simulate these phenomena and establish the linkage among these models. In order to model petroleum migration through faults and fractures, we have developed forward geomechanical model which calculates stress-strain condition and plastic-elastic deformation. We adapted cam-clay model developed in civil engineering. Our case study indicated that this model can simulate work-softening and work-hardening effects, which corresponds to the fault acting as leakage and as seal, respectively. It was also modeled that one fault has both work-softening and hardening portions at the same time according to stress-strain condition. Source-rock distribution and its properties are important and sensitive input data for petroleum migration model. However, at this moment, users have to specify them with limited information and in some cases, it is difficult to do it. Therefore, source-rock depositional model, which calculates water circulation, organic matter production and preservation, has been also developed. Our case study in present Lake Tanganyika indicated that modeled water circulation and organic matter production and concentration are consistent with observed ones. We have just started to include the function to model the formation of methane hydrate into petroleum migration model, which would be additional evolution of petroleum system modeling
10837 Chemiluminescence Analysis from In-Cylinder Combustion of a DME-Fueled DI Diesel Engine SAE Powertrain & Fluid Systems Conference
2003/10/29
Mitsuaru Oguma, Shinichi Goto (National Institute of Advanced Industrial Science and Technology), Hidefumi Hatsuzawa, Zhili Chen, Mitsuru Konno (Ibaraki University), Tomoko Watanabe (Japan National Oil Corporation) Research Project Team for Emerging Gas Technologies
[Abstract] To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength. This baseline intensity seems to be continuous spectrum emission. Two emission intensity peaks were observed; one near 427 nm and the other at 431.4 nm, and these were apparently DME combustion emission lines. The intensity of the 427 nm line increases from the early to middle stage of diffusion combustion, compared to the continuous spectrum. As combustion advances, the light intensity strengthens around the combustion chamber walls. That is, active heat release occurs near the chamber walls.
10836 A Trial of delineation of Methane Hydrate-bearing Zone using Seismic Attribute -For Quantification of Methane Hydrate Volume- 1st International Workshop on Continental Margin Tectonics and Gas Hydrates
2003/11/16-18
Masami Hato, Takao Inamori (Japan Petroleum Exploration Co., Ltd.), Jun Matsushima (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] Following the confirmation of methane hydrate (hereafter called just as ehydratef) occurrence in Nankai Trough offshore Japan by drilling in 1999, the national project named eMH21f started. The most important and hurried issue to be done is to evaluate the total amount of the hydrate after establishing the geophysical evaluation technique.
Due to the style of the hydrate accumulation, we can easily find the bottom of hydrate-bearing zone by BSR. On the other hand, the top of the hydrate-bearing zone is hard to recognize because of its sparse distribution. Hato & Inamori (2002) introduced the validity of the interval velocity to delineate spatial distribution of hydrate based on the high impedance property of the hydrate.
In order to try more precise delineation of hydrate-bearing zone, we adopt a seismic attribute. Attribute analysis is categorized into 2 class, which is post-stack attribute and pre-stack attribute analysis. In this presentation, we show the result of post-stack hybrid (impedance and attenuation) attribute analysis to the seismic data acquired in Nankai Trough, based on the fact of high impedance of hydrate-bearing zone and hypothesis of low elastic-wave attenuation in the hydrate. This hybrid attribute well indicates the hydrate-bearing interval except some hydrate-bearing layers. We also tried to apply a pre-stack hybrid (impedance and pseudo Poissonfs ratio) attribute analysis to the same data based on the purely theoretical approach. The result shows us good coincidence to the result from the post-stack attribute analysis and the well log analysis.
10835 Seismic features of BSRs in Nankai Trough, offshore Japan 1st International Workshop on Continental Margin Tectonics and Gas Hydrates
2003/11/16-18
Shoshiro Shimizu, Nobutaka Oikawa, Masao Hayashi, Koji Ochiai, Masaru Nakamizu, Yoshihiro Tsuji (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] In general, pressure and temperature conditions below water depths of about 500 m, cause methane to form ice-like crystals of methane hydrate. If methane hydrate is formed in unconsolidated sedimentary layer, its P-wave velocity becomes much higher than surrounding layers, and the velocity structure of methane hydrate will give its existence on the seismic section. In this stage, marine seismic survey is the key in the point of view that the seismic reflector on a seismic section is recognized as the indicator to exist a methane hydrate and it is called the bottom simulating reflector (BSR).
BSRs were recognized on the seismic section of the continental margin of Nankai Trough, at 1980s (Aoki Y. et al 1983) and the extensive distribution of BSRs were anticipated on this area (Ciesnik N. et al 1989).
In Japan, the methane hydrate research project had commenced from 1995 and continued to 2000 as Special Research “Methane Hydrate Exploration Technology”, and consecutively “MH21” research project had started 2001 FY and will continue to 2006 FY as the Phase-1. The objective of these projects is to investigate the possibility of the methane hydrate offshore Japan as energy resources. In theses projects, various types of seismic surveys to delineate precise distribution of BSRs were carried out in the continental margin of Nankai Trough, and it was clear that the BSRs have various appearances by different seismic surveys, for example deep-towed seismic survey, OBS, conventional and high resolution seismic surveys. We will show some examples of seismic sections acquired by the above mentioned surveys, and the validity of such surveys has been examined. BSRs themselves also are evaluated by their continuity, strength of amplitude and frequency contents of them to select a proper area of methane hydrate exploration.
10834 Assessment of the Resource Potential of Methane Hydrate in the Nankai Trough, offshore Central Japan Fire in Ice: Implication for Energy Development and the Carbon Cycle? Gas Hydrate Workshop
2003/11/12
Yoshihiro Tsuji (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] Efforts on resource assessment of methane hydrate in the Nankai Trough area, offshore Central Japan, was introduced. The occurrence of methane hydrate in the exploratory well, MITI "Nankai Trough", and of BSRs observed in the data of 2D and 3D seismic survey were also presented.
10832 Observation of natural gas hydrate dissociation with X-ray CT International Workshop on X-ray CT Geomaterials (Geox 2003)
2003/11/7
Toshiharu Okui (Japan National Oil Corporation), Takashi Uchida (Japan Petroleum Exploration Co. Ltd.), Yoshihiro Masuda (University of Tokyo) Research Project Team, Methane Hydrate
[Abstract] Dissociation of gas hydrate, which has drawn much attention as an unconventional energy resource, in natural core samples from permafrost was observed with an X-ray CT scanner. Both depressurizing and heating processes, which are considered as typical potential production processes, were simulated in laboratory scale for the field gas production tests from gas hydrate. Dissociation of the gas hydrate was clearly observed as difference of CT values. The difference was mainly caused by gas phase formation. Ob-tained three-dimensional CT data of inside of the cores were processed to visualize dissociation behavior. Consequently it was observed that dissociation behavior depended on quantity and distribution of hydrates. These results suggested that X-ray CT scanning was suitable for observation of natural gas hydrate dissocia-tion in sediments and useful for evaluation of gas hydrate as an unconventional energy in future.
10831 Occurrence of Methane Hydrate and BSRs in the Nankai Trough, offshore Japan Geological Society of America
2003/11/5
Yoshihiro Tsuji, Koji Ochiai, Takatoshi Namikawa, Shoshiro Shimizu, Masao Hayashi, Nobutaka Oikawa, Masaru Nakamizu, Jun Matsushima (Japan National Oil Corporation), Toshihide Shimizu (Teikoku Oil Co., Ltd.), Ken Shibata(Japan Petroleum Exploration) Research Project Team, Methane Hydrate
[Abstract] As a part of a project assessing resource potential of methane hydrate which is expected to be associated with widely distributed BSRs (Bottom Simulating Reflectors) in the Northwest Pacific, offshore Central Japan, the MITI Exploratory test well "Nankai Trough" drilling campaign was carried out from late 1999 to early 2000, at the water depth of 945m. During the drilling campaign, a total of six wells were drilled within a 100m radius of the main hole: two pilot holes, the main hole, and three post survey wells. Distances among each hole are 10m to 100m. Wireline logging, LWD and/or coring were carried out and logging records and core analyses data were obtained from the wells. Based on the results of Resistivity, Sonic, FMI, CMR, and other logging data which are very effective for methane hydrate evaluation, it was determined that there were four methane hydrate bearing sand rich intervals, and total thickness of the methane hydrate rich beds is 12 to 14m. Such intervals consist of turbidite fan deposits. The intervals were correlated between the wells, and wireline logging data showed that the methane hydrate saturation was 20 to 80% in the layers. The bottom depth of high hydrate concentration was correlated with the depth of BSR by VSP. Methane hydrate occurrence to fill pore spaces among grains, an advantage for resource point of view, was visually confirmed by cores from two wells. It has been revealed that BSR has various features, that is, variety in amplitude and continuity, which is presumably influenced by methane hydrate concentration and occurrence in the sediments. To obtain the reliable volume for methane hydrate resource, it is necessary to correlate and calibrate the subsurface geological information from wells and BSRs. The characteristics of BSRs and their distribution were examined using 2D and 3D seismic data, and plan for multi-well drilling campaign in early 2004 were settled to verify methane hydrate occurrences with related to BSRs.
10829 Development of a compact and high-efficiency DME-fueled fuel cell reforming system 2003 Fuel Cell Seminar
2003/11/4
Tetsuya Takemoto, Osamu Okada (Osaka Gas Co., Ltd.), Yasushi Hiramatsu (Mitsubishi Gas Chemical Co., Inc), Hiroshi Hashimoto (JGC Corporation), Hisashi Otsuka (Itochu Corporation), Shinichi Suzuki (Japan National Oil Corporation) R&D Planning Division
[Abstract] With its high chemical stability, extremely low toxicity and physical properties similar to liquefied petroleum gas, dimethyl ether (hereinafter referred to as “DME”) is a promising synthetic fuel. DME can also be a favorable energy carrier in light of effective utilization of small and medium-scale gas fields untapped due to economic constraints, such as high transport costs. To take advantage of these excellent characteristics, extensive efforts have been made to develop and improve DME manufacturing techniques, and develop application technologies to promote the use of DME. Meanwhile, in the field of fuel use technologies, development of clean, energy-saving technologies for consumer use is an urgent task. As part of such efforts, researchers have been working to develop polymer electrolyte fuel cell systems for domestic and automobile use.
Focusing our attention on DME, which is expected to offer extensive applications, we are aiming to develop a compact and high-efficiency fuel cell system that uses DME as a fuel. To this end, our efforts have been focused on the development of a DME reforming unit, and the downsizing and improved efficiency of existing reforming systems. We have been conducting research and development on: 1) a DME reforming catalyst, 2) a CO selective oxidation high-efficiency heat removal system, and 3) a comprehensive fuel-cell system, and concurrently conducting market research on a DME fuel cell. With focus on development of a DME reforming catalyst, this paper reports on our DME fuel cell system.
10827 Implementation of the Extended Leak-off Test in Deep Wells in Japan International Symposium on Rock Stress Kumamoto (RS Kumamoto 2003)
2003/11/4
kohji Yamamoto (Japan National Oil Corporation) Research Division for Petroleum Engineering
[Abstract] Some experiences of carrying out the Extended Leak-off Test (ELOT) in two deep exploration wells drilled in Japan, in northern Hokkaido and Niigata prefecture, are presented with an evaluation of the stress states. Different pressure records obtained in the wells and depths are shown, and evaluation procedures considering the geological features of the relevant formation are described. The authors propose a modified procedure of the test for improving the accuracy of the interpretation and ensuring the well integrity.
10826 Characteristics of Spray Formation and Combustion in Diesel Engines Operated with Dimethyl Ether 6th IDA Meeting
2003/11/14
Yuji Oda, Koutaro Fujimura (Mitsubishi Heavy Industries, Ltd.), Shuichi Kajitani (Ibaraki University), Shinichi Suzuki (Japan National Oil Corporation) Research Project Team for Emerging Gas Technologies
[Abstract] In this paper, characteristics of dimethyl ether spray formation was observed by the high speed video and both of the combustion characteristics and performance of the dimethyl ether operated diesel engine were investigated. From the observational results on dimethyl ether spray, it becomes clear that the spray formation is so much different from that of gas oil and that is the point to be specially considered in designing the combustion system. From the experimental result using dimethyl ether operated diesel engine, it becomes clear that it can achieve the smokeless performance under whole driving condition. In addition, even with large amount of EGR, it keeps smokeless performance, and it was obtained that it could pass the EPA Tier3 exhaust regulation. Throughout these experiments, the abrasive characteristics in fuel injection system, especially on the fuel injection pump plunger surface and on the fuel injection valve needle surface, is also confirmed and the necessity of some coating treatment is predicted. From these results, the basic characteristics of engine performance, the potential ability of decreasing exhaust emission and also the problems in the dimethyl ether operated diesel engine for practical use are discussed.
10825 Characteristics of Spray Formation and Combustion in Diesel Engines Operated with Dimethyl Ether Shanghai DME Forum 2003
2003/10/23
Yuji Oda, Koutaro Fujimura (Mitsubishi Heavy Industries, Ltd.), Shuichi Kajitani (Ibaraki University), Shinichi Suzuki (Japan National Oil Corporation) Research Project Team for Emerging Gas Technologies
[Abstract] In this paper, characteristics of dimethyl ether spray formation was observed by the high speed video and both of the combustion characteristics and performance of the dimethyl ether operated diesel engine were investigated. From the observational results on dimethyl ether spray, it becomes clear that the spray formation is so much different from that of gas oil and that is the point to be specially considered in designing the combustion system. From the experimental result using dimethyl ether operated diesel engine, it becomes clear that it can achieve the smokeless performance under whole driving condition. In addition, even with large amount of EGR, it keeps smokeless performance, and it was obtained that it could pass the EPA Tier3 exhaust regulation. Throughout these experiments, the abrasive characteristics in fuel injection system, especially on the fuel injection pump plunger surface and on the fuel injection valve needle surface, is also confirmed and the necessity of some coating treatment is predicted. From these results, the basic characteristics of engine performance, the potential ability of decreasing exhaust emission and also the problems in the dimethyl ether operated diesel engine for practical use are discussed.
10818 Characteristics and Impact of Asphaltene Precipitation During CO2 Injection in Sandstone and Carbonate Cores: An Investigative Analysis Through Laboratory Tests and Compositional Simulation SPE International Improved Oil Recovery Conference in Asia Pacific
2003/10/21
Satoru Takahashi (Japan National Oil Corporation) Research Division for Petroleum Engineering
[Abstract] Characteristics and impact of asphaltene precipitation during CO2 injection were investigated for a Middle East crude oil in both sandstone and carbonate cores through phase behavior studies, corefloods and analyses of the deposition process using a compositional simulator. In phase behavior studies, a light-scattering technique with near infrared was used to determine the onset pressure of asphaltene precipitation. Also investigated were the effects of CO2 concentration on precipitation, including the potential for precipitation by CO2 at the current reservoir pressure.
The coreflood tests were conducted above the minimum miscibility pressure (MMP) in both carbonate and sandstone cores to investigate any difference in asphaltene precipitation characteristics in them. The asphaltene content in the produced oil decreased after the CO2 breakthrough -- an indication of its precipitation within the core. A careful post-test analysis of the flooded cores revealed that a larger amount of asphaltene was left behind in carbonate cores than sandstone core.
A compositional simulation study with tuned EoS parameters was carried out to evaluate coreflood results, followed by a parametric sensitivity analysis. In addition, the effects of rock heterogeneities on the oil recovery and asphaltene precipitation were investigated. A good match with the oil recovery was obtained. Results indicated that higher the degree of heterogeneities, the higher is the asphaltene accumulation in the core.
10817 Three-dimensional seismic imaging of bottom-simulating reflectors by multi-channel seismic survey in the Nankai accretionary prism SEG (Society of Exploration Geophysicists) 73rd Annual Meeting
2003/10/29
Jun Matsushima, Shoshiro Shimizu, Nobutaka Oikawa, Masao Hayashi, Koji Ochiai, Masaru Nakamizu(Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] A three-dimensional (3-D) multi-channel seismic (MCS) survey was carried out in 2002 by METI (Ministry of Economy, Trade and Industry) to explore gas hydrate bearing sediments and to provide information contributed to the drilling campaign scheduled in 2003 on the Nankai Trough area, Japan. The seismic data presented here show the 3-D distribution of bottom simulating reflectors (BSRs), which are associated with the base of the hydrate stability zone and are expressed on seismic records as a strong reflection of negative polarity, often crosscutting stratigraphic layers. Our 3-D MCS data indicate the widespread existence of methane hydrate through the presence of BSRs. From the preliminary interpretation of the 3-D distribution of BSRs, we found structural disturbances in the BSRs, which could be related to land slide. We finally concluded that 3-D imaging of BSRs proved to be useful in tracing the 3-D continuities of BSRs.
10811 Development of Transient Cuttings Transport & Hydraulics simulator for UBD SPE Applied Technology Workshop “Underbalanced Operations”
2003/9/21-24
Katsuhiro Ohbi (Japan National Oil Corporation) Research Division for Petroleum Engineering
[Abstract] JNOC/TRC has performed to develop the technology related to “Transient Hydraulics Simulator (THS)” and “Cuttings Transport Simulator (CTS)” with underbalanced drilling using the experimental facility “Cuttings Transport Flow Loop System (CTFLS)”. “THS” which applys drift-flux model includes transient multiphase hydraulics in a drill string and annulus and predicts BHP accurately. “CTS” which applys two-layer model and expand to 3 phase ?2 layer model can caluculate the Cuttings concentration, each phase velocity and pressure in the annulus.
Those two simulators are trying to integrate and improve now.
10809 High resolution, deep-tow seismic survey to investigate methane hydrate-bearing sediments, Nankai Trough, offshore Japan OMARC (Ocean Margin Research Conference)
2003/9/15-17
Eiichi Asakawa, Peter Ward (JGI Inc.), Shoshirou Shimizu (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] A 2D deep-towed seismic survey was carried out over part of the Nankai Trough, Offshore Japan, in 1996. The area is known to have a major accumulation of methane hydrate; conventional seismic surveys have mapped thousands of sq. km. of BSR events, and the presence of methane hydrate was confirmed by a MITI research well in 2000.
The objective of the deep-towed survey was to obtain high-resolution stack and velocity profiles of the methane hydrate-bearing sediments down to the BSR, which occurs at around 300 msec below the sea bottom in this area.
The data was acquired using the "Deep-Towed Acoustics/Geophysics System (DTAGS), developed by the Naval Research Laboratory, USA. Both the source and the hydrophone cable are towed close to the seabed, allowing a "close look" at the shallow sediments. The source is a vibrator-type Helmholtz transducer with a 0.25 sec sweep from 250-650 Hz. The hydrophone cable has 48 channels and a maximum offset of 620m.
This paper focuses on the data processing, carried out in 1998 and 2002. The main challenge in the processing was to handle the floating acquisition datum with source and receiver depths being maintained at typically 200-300 m above a varying seabed. The measured depths had to be corrected by residual statics derived from picks of the sea bottom reflection event. A total of around 200 km of data was processed, with water depths of 700-1400 m. The results showed that it is possible to obtain high-resolution profiles and velocity data, and that it is also possible to fail to achieve such data. Success largely depends upon control of the depths during acquisition; they should be kept smoothly varying and measured as accurately as possible.
The deep-tow system has the advantage over conventional data in water depths of around 1000 m or deeper, for zones close (within 100fs m) to the seabed. The advantage of the system becomes greater with increasing water depth.
10806 An Appraisal Project for offshore Methane Hydrate around Japan AAPG International Conference
2003/9/23
Takatoshi Namikawa, Yoshihiro Tsuji, Masaru Nakamizu, Koji Ochiai (Japan National Oil Corporation) Research Project Team, Methane Hydrate
[Abstract] Based on the interpretation result of many of seismic records BSR (Bottom Simulated reflector), which is considered as an index of methane hydrate, is detected in many of seismic records in offshore Japan. According to a certain trial calculation the amount of methane resource can be 250tcf in place. It is one of the largest potential hydrocarbon resources for Japan. Therefore, as a part of Japanfs Methane Hydrate Exploitation Program, Japan National Oil Corporation (JNOC) has been generating an appraisal project for offshore methane hydrate. This project consists from 2D, 3D seismic and series of exploratory test wells. 2D (2800km) and 3D (1960km2) seismic were acquired in 2001 and 2002. Exploratory test wells those will be drilled in early 2004. Data from those activities provides input data to calculate the amount of resource and information for site selection for future production test well.
10805 Integration of Three-dimensional Petroleum Migration Model, Geomechanical Model and Source Rock Depositional Model -Challenge for the Development of Full Petroleum System Model- AAPG International Conference Barcelona 2003
2003/9/22
Akihiko Okui, Kunihiro Tsuchida, Ryosuke Aoyagi (Japan National Oil Corporation), Noboru Yamazaki, Osamu Kitamura, Kiyoshi Matsubara (Fuji Research Institute Corporation) Research Project Team, Methane Hydrate
[Abstract] Basin modeling technique was started in 70fs as zero-dimensional source rock maturity model, and has evolved to one-dimensional model introducing compaction, heat transfer and kinetic model and to two-dimensional model with fluid flow. Even three-dimensional petroleum migration model has been developed in late 90fs and started using in actual exploration and production projects in oil companies.
However, present three-dimensional petroleum migration model is not perfect and lacking enough capability to model essential phenomena in petroleum system such as petroleum migration through faults and fractures, and source rock development. Our solution is to develop additional computer models to simulate these phenomena and establish the linkage among these models.
In order to model petroleum migration through faults and fractures, we have developed forward geomechanical model which calculates stress-strain condition and plastic-elastic deformation. We adapted cam-clay model developed in civil engineering. Our test indicated that this model can simulate work-softening (fault leak) and work-hardening (fault seal) effects.
In order to model source rock development, we have developed source rock depositional model which calculate water circulation, organic matter production and preservation. Our case study in present Lake Tanganyika that this model can simulate observed water circulation and organic matter production and preservation.
These new two model will be combined with our three-dimensional petroleum migration model and case studies in actual geological basin will be conducted soon.
10804 The Challenge Of JNOC To Develop The New GTL Process GAS-TO-LIQUID VI Conference
2003/9/10-11
Masaru Ihara, Yoshifumi Suehiro, Kazuhito Katakura (Japan National Oil Corporation), Toshiya Wakatsuki (Japan Petroleum Exploration Co., Ltd.), Mitsunori Shimura (Chiyoda Corporation), Toshio Shimizu (Cosmo Oil Co., Ltd.), Kenichiro Fujimoto (Nippon Steel Co., Ltd.), Atsushi Sakamoto (INPEX Corporation), Suhardiman, Kusmiyati, Satya A.Putra, J.H.Simamora, Budiyono, Musalam L, A.H.Kusnadi, T.Suhartanto, Soewarto, L.Nainggolan (PERTAMINA) Research Project Team for Emerging Gas Technologies
[Abstract] The natural gas with clean characteristics in combustion is expected to be the alternative energy resources to oils in the near future and further promotion of its utilization will also be beneficial to environmental preservation.
JNOC has been tackling the research and development of the natural gas conversion technology from the year of 1998 till 2004 in collaboration with five Japanese private companies such as JAPEX, CHIYODA, COSMO OIL, NIPPON STEEL and INPEX, in order to aim at establishing the option technology to explore stranded gas reserves.
The JNOC-GTL process differs from other GTL processes in two main sections:
1) The synthetic gas production (Syngas) section applies the steam (H2O)/CO2 reforming rather than Auto-thermal Reforming (ATR) or Non-catalytic Partial Oxidation (POX) used in other processes, and
2) The Fischer-Tropsche synthesis (FT) section employs the slurry reactor with noble metal or non-noble metal catalysts, as compared to the Co or Fe based catalysts used in other processes.
Thus, JNOC-GTL process is expected to get prominently effective in energy efficiency as applied against the natural gas reserves containing relatively high CO2.
JNOC-GTL process is capable to utilize CO2 contained in the natural gas and does not require any O2 supply. Namely, the characteristics of JNOC-GTL process in contrast to those of the existing ones using ATR or POX are (1) no use of the O2 generator, (2) no use of the CO2 removal unit, and (3) no use of the H2 conditioning unit for syngas.
Such facility savings will bring about the remarkable reduction of the plant cost for its election and operation. The suitable conditions for the JNOC-GTL process will meet with the plant scale of 5,000-15,000 BPSD and the case of CO2 contents being 20-40 mol% in the natural gas. The economic evaluation does indicate that the JNOC-GTL process is more economical than the conventional ones when applied under those conditions.
Our challenges conducted until now have produced the promising Syngas and FT catalysts and attained the efficient total process.
This paper introduces the outline and the characteristics of JNOC-GTL process, the results of Syngas and FT catalysts, process development, the part of the results of the Yufutsu GTL pilot plant tests, and the economic evaluation emphasizing Feasibility Study with Pertamina.
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